Selective Demethylation of 3-Phenoxyquinoxalin-2(1h)-one Acetate Derivatives

机译：3-苯氧喹喔啉-2（1H）的选择性去甲基化 - 醋酸盐衍生物

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Using the previously reported novel quinoxaline scaffold, we synthesised the precursor compounds 1-12. According to the synthetic methodology, we described the discovery of a novel selective demethylation of quinoxaline derivatives with AlCl_3 and BBr_3, proposed a high selectivity demethylation approach. And this approach will provide a opportunity for developing new antioxidant base on phenolic hydroxyl.

机译：使用先前报道的新型喹喔啉支架，我们合成前体化合物1-12。根据合成方法，我们描述了将喹喔啉衍生物与AlCl_3和BBR_3的新选择性去甲基化的发现发现，提出了一种高选择性去甲基化方法。这种方法将为在酚羟基上开发新的抗氧化碱的机会。

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《International Conference on Industrial Technology and Management Science》|2015年|967p|共2页
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Yingang ZOU; Bing MA;
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中图分类 T-53;
关键词
Demethylation; Diabetes; Quinoxaline;

机译：去甲基化;糖尿病;喹喔啉;

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专利

1. Phenolic 4-hydroxy and 3,5-dihydroxy derivatives of 3-phenoxyquinoxalin-2(1H)-one as potent aldose reductase inhibitors with antioxidant activity [J] . Zou Yingang, Qin Xiangyu, Hao Xin, Bioorganic and Medicinal Chemistry Letters . 2015,第18期

机译：3-苯氧基喹喔啉-2（1H）-one的酚4-羟基和3,5-二羟基衍生物作为具有抗氧化活性的有效醛糖还原酶抑制剂
2. Design, synthesis, and biological evaluation of new 1,8-naphthyridin-4(1H)-on-3-carboxamide and quinolin-4(1H)-on-3-carboxamide derivatives as CB2 selective agonists [J] . Manera C, Benetti V, Castelli MP, Journal of Medicinal Chemistry . 2006,第20期

机译：新的1,8-萘啶-4（1H）-on-3-羧酰胺和喹啉-4（1H）-on-3-羧酰胺衍生物作为CB2选择性激动剂的设计，合成和生物学评估
3. Selective Hydrogenolysis of Furfural Derivative 2-Methyltetrahydrofuran into Pentanediol Acetate and Pentanol Acetate over Pd/C and Sc(OTf)(3) Cocatalytic System [J] . Zhang Kun, Li Xing-Long, Chen Shi-Yan, ChemSusChem . 2018,第4期

机译：PD / C和SC（OTF）（3）助催化系统的戊二醇乙酸戊酯和戊醇乙酸戊酯和戊醇的选择性氢解
4. Selective Demethylation of 3-Phenoxyquinoxalin-2(1h)-one Acetate Derivatives [C] . Yingang ZOU, Bing MA International Conference on Industrial Technology and Management Science . 2015

机译：3苯氧基喹啉-2（1H）的选择性去甲基化 - 醋酸盐衍生物
5. SYNTHESIS AND SELECTIVE DEMETHYLATION OF CATECHOL ETHERS DURING ACID-CATALYZED CYCLIALKYLATION. [D] . VICKERY, EUIN HAROLD, JR. 1979

机译：酸催化环烷基化过程中邻苯二酚醚的合成和选择性脱甲基。
6. Discovery of Novel 5-(Piperazine-1-carbonyl)pyridin-2(1H)-one Derivatives as Orally eIF4A3-Selective Inhibitors [O] . Ryo Mizojiri, *, Daisuke Nakata, 2017

机译：新型5-（哌嗪-1-羰基）吡啶-2（1H）-一衍生物作为口服eIF4A3选择性抑制剂的发现
7. Selective Demethylation of 3-Phenoxyquinoxalin-2(1h)-one Acetate Derivatives [O] . Yingang Zou, Bing Ma 2015

机译：3苯氧基喹啉-2（1H）的选择性去甲基化 - 醋酸盐衍生物

Selective Demethylation of 3-Phenoxyquinoxalin-2(1h)-one Acetate Derivatives

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