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A strong and sticky hydrogel electrolyte for flexible supercapacitors

机译:用于柔性超级电容器的强粘稠水凝胶电解质

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With the rapid development of flexible supercapacitors (SCs), there is increasing demand for highperformance solid electrolyte to replace the conventional liquid electrolyte. Hydrogel electrolyte is one of the promising candidates, which possesses solid state but contains plenty of water within its highly porous structure. In this paper, a strong and sticky hydrogel has been synthesized using bacterial cellulose (BC) and poly (acrylic acid) (PAA). The results of attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy shows that two components are well combined. Scanning electron microscopy (SEM) test shows that BC/PAA has a highly porous structure, which is modified by the interaction between BC nanoflbers and acrylic acid monomer. Double network created by BC and PAA not only enhances the mechanical property of PAA but also improves the anti-compression ability of BC. Moreover, a sticky property is recognized within BC/PAA due to PAA, which can prevent the spilt of two flexible electrodes. The high ionic strength makes PAA shrink in 1M Na_2SO_4. However, the swelling ratio of BC/PAA could still reach to approximately 500% and its ionic conductivity is about 0.06 S·cm~(-1). This prepared BC/PAA hydrogel electrolyte has a great potential to be used in flexible SCs
机译:随着柔性超级电容器(SCS)的快速发展,对高性能固体电解质的需求越来越大,以取代常规液体电解质。水凝胶电解质是有希望的候选物之一,其具有固态,但在其高度多孔结构中含有大量的水。在本文中,使用细菌纤维素(BC)和聚(丙烯酸)(PAA)合成了强粘性水凝胶。减振总反射率傅里叶变换红外(ATR-FTIR)光谱的结果表明,两个组分合并得很好。扫描电子显微镜(SEM)试验表明,BC / PAA具有高度多孔结构,其通过BC纳米帘和丙烯酸单体之间的相互作用而改性。 BC和PAA创建的双网络不仅增强了PAA的机械性能,还提高了BC的抗压缩能力。此外,由于PAA,在BC / PAA内识别粘性性能,这可以防止两个柔性电极的溢出。高离子强度使得PAA收缩1M Na_2SO_4。然而,BC / PAA的溶胀比率仍然达到约500%,其离子电导率约为0.06秒·cm〜(-1)。该制备的BC / PAA水凝胶电解质具有在柔性SCS中使用的很大潜力

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