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Preparation and Modification of Polystyrene/Clay Nanocomposite Using Ethylene Octene Copolymer and SBS Block Copolymer

机译:乙烯辛烯共聚物和SBS嵌段共聚物的聚苯乙烯/粘土纳米复合材料的制备与改性

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Polystyrene/clay nanocomposites were prepared and modified by SBS and catalyzed metallocene ethylene octene copolymer. The results indicated an improvement in mechanical properties of the nanocomposite contained 1 w% of nanoclay. X- Ray analysis revealed that only intercalated structures were found in the nanocomposites. Scanning electron microscopy (SEM) showed a homogenous morphology for the nanocomposites due to compatibility between polystyrene and styrene butadiene styrene. Energy dispersive X-ray (EDX) analysis also confirmed a sufficient dispersion and distribution of Si elements from nanoclay in the PS/SBS matrix. Thermal stability of the nanocomposites was studied by heat deflection temperature (HDT) and also thermo gravimetric analysis (TGA). It was found that HDT and thermal degradation were enhanced for the nanocomposite which was contained 1 w% of clay nanoparticles compared to the neat polystyrene.
机译:制备聚苯乙烯/粘土纳米复合材料并通过SBS和催化的茂金属乙烯辛烯共聚物改性。结果表明纳米复合材料的机械性能提高含有1w%的纳米粘土。 X射线分析显示,在纳米复合材料中发现了仅嵌入结构。由于聚苯乙烯和苯乙烯丁二烯苯乙烯之间的相容性,扫描电子显微镜(SEM)显示了纳米复合材料的均匀形态。能量分散X射线(EDX)分析还确认了从PS / SBS基质中的纳米粘土中的足够分散和分布。通过热偏转温度(HDT)研究了纳米复合材料的热稳定性,以及热重量分析(TGA)。发现与纯聚苯乙烯相比,纳米复合材料增强了HDT和热劣化,其含有1W%的粘土纳米粒子。

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