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Gas Adsorption Properties of Cyanide-Bridged Nanoporous Metal Complexes with Coordinatively Unsaturated Metal Sites

机译：氰化物桥面纳米多孔金属配合物与协调不饱和金属位点的气体吸附性能

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Nanoporous metal complexes (NPCs) as new class of porous crystalline materials have received considerable attention in recent years. NPCs are consisted of metal ions as versatile connectors and bridging organic or metallo-ligands as linkers that are connected into frameworks based on coordination bonds with the aid of other interactions, such as hydrogen/metal-metal bonds, π-π, CH-π, electrostatic, and van der Waals interactions. NPCs are promising candidates in many fields such as gas storage, separation, and heterogeneous catalysis due to their high pore volume, large surface area and flexible framework.

机译：纳米多孔金属配合物（NPC）作为新一类多孔晶体材料近年来受到相当大的关注。 NPC由金属离子组成，作为多功能连接器和桥接有机或金属配体，作为基于其他相互作用的基于配位键连接到骨架中的接头，例如氢/金属 - 金属键，π-π，CH-π ，静电和范德瓦尔斯相互作用。由于其高孔体积，大表面积和柔性框架，诸如储气，分离和异质催化等许多领域的候选人是有前途的候选者。

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来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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Akio Mishima; Akihiro Hori; Yunsheng Ma;
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正文语种
中图分类石油化学工业;
关键词
Nanoporous Metal Complex; Adsorption Property;

机译：纳米多孔金属络合物;吸附性质;

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1. Adsorption Characteristics of Metal-Organic Frameworks Containing Coordinatively Unsaturated Metal Sites: Effect of Metal Cations and Adsorbate Properties [J] . Prashant Mishra, Satyannarayana Edubilli, Bishnupada Mandal The journal of physical chemistry, C. Nanomaterials and interfaces . 2014,第13期

机译：包含配位不饱和金属位点的金属有机骨架的吸附特性：金属阳离子和吸附质的影响
2. Coordinatively Unsaturated Metal Site-Promoted Selective Adsorption of Organic Molecules on Supported Metal-Organic Framework Nanosheets [J] . Zha Jie, Yin Xinyang, Baltzegar Jacob R., Langmuir: The ACS Journal of Surfaces and Colloids . 2019,第40期

机译：协调性不饱和金属位点 - 促进了有机分子对负载金属 - 有机框架纳米片的选择性吸附
3. Metal-Organic Framework-Polymer Composite as a Highly Efficient Sorbent for Sulfonamide Adsorption and Desorption: Effect of Coordinatively Unsaturated Metal Site and Topology [J] . Shih Yung-Han, Wang Kuen-Yun, Singco Brenda, Langmuir: The ACS Journal of Surfaces and Colloids . 2016,第44期

机译：金属-有机骨架-聚合物复合材料作为磺酰胺吸附和解吸的高效吸收剂：不饱和金属位点和拓扑结构的影响
4. Gas Adsorption Properties of Cyanide-Bridged Nanoporous Metal Complexes with Coordinatively Unsaturated Metal Sites [C] . Akio Mishima, Akihiro Hori, Yunsheng Ma 日本化学会春季年会講演予稿集 . 2018

机译：氰化物桥面纳米多孔金属配合物与协调不饱和金属位点的气体吸附性能
5. METAL ATOM CHEMISTRY: SYNTHESIS, ISOLATION AND REACTIONS OF COORDINATIVELY UNSATURATED ORGANOMETALLIC COMPLEXES; ORGANOMETALLIC COMPLEXES CONTAINING BOTH SIGMA AND PI BONDS. [D] . ANDERSON, BRUCE BEARDSLEY. 1980

机译：金属原子化学：协同不饱和有机金属配合物的合成，分离和反应；包含SIGMA和PI债券的有机复合物。
6. Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes [O] . G. F. Schmidt, E. L. Muetterties, M. A. Beno, 1981

机译：配位不饱和多核金属配合物中的烷基金属和芳基金属键化学
7. Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites: Sorption Properties for Various Gases [O] . -1

机译：具有协调不饱和MnII位点的多孔金属 - 有机框架：各种气体的吸附性能
8. Analogies Among Active Sites of Coordinatively-Unsaturated Transition-Metal Complexes, Surfaces and Supported Catalysts. [R] . Johnson, K. H., Balazs, A. C., Kolari, H. J. 1977

机译：在配位 - 不饱和过渡金属配合物，表面和负载型催化剂的活性位点中的类比。

Gas Adsorption Properties of Cyanide-Bridged Nanoporous Metal Complexes with Coordinatively Unsaturated Metal Sites

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