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Systematic evaluation of tetraalkylammonium salts on the synthesis and reactivity of titanate nanosheets

机译：四烷基铵盐对钛酸盐纳米液合成及反应性的系统评价

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Titanate nanosheets (TNS) synthesized in liquid phase are uniformed rhomboidal shape, and have high water-dispersibility and photocatalystic property. We use tetraethylammonium hydroxide (NEt4-OH) as dispersing and capping agents in synthesis of TNS. Tetraethyl- ammonium cations (NEt4 + ) play the role of above agents because they can interact the surface negative charge of TNS. But, we didn’t know the role of hydroxide anions (OH- ) in synthesis. In order to confirm the role of OH- in TNS synthesis, we synthesized TNS dispersions including other anions and systematically evaluated the shapes and reactivity of these TNSs.

机译：在液相中合成的钛酸钛烯片（TNS）是均匀的菱形形状，具有高水分散性和光催化性能。我们在合成TNS中使用氢氧化铵（NET4-OH）作为分散和封端剂。四乙基 - 铵阳离子（NET4 +）起到上述药剂的作用，因为它们可以相互作用TNS的表面负电荷。但是，我们不知道氢氧化物阴离子（OH-）在合成中的作用。为了确认OH-在TNS合成中的作用，我们合成了包括其他阴离子的TNS分散体，并系统地评估这些TNS的形状和反应性。

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来源
《日本化学会春季年会講演予稿集》|2018年|1 CD-ROM|共1页
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作者
Daisuke Yoshioka; Yasumitsu Nishimura;
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正文语种
中图分类石油化学工业;
关键词
Titanate Nanosheets; Tetraalkylammoium Salts; Water Dispersibility; Photo- induced Redox Reaction;

机译：钛酸纳米甲板;四烷基铵盐;水分散性;光诱导的氧化还原反应;

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1. Molten salt synthesis of the lead titanate PbTiO3, investigation of the reactivity of various titanium and lead salts with molten alkali-metal nitrites [J] . Aboujalil A., Chassagneux F., Scharff JP., Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 1998,第7期

机译：钛酸铅PbTiO3的熔融盐合成，各种钛盐和铅盐与熔融碱金属亚硝酸盐的反应性研究
2. Tailored Hydrothermal Synthesis of Specific Facet-Dominated TiO2 Nanocrystals from Lepidocrocite-Type Layered Titanate Nanosheets: Systematical Investigation and Enhanced Photocatalytic Performance [J] . Xu Linfeng, Fang Hongjun, Li Sen, Langmuir: The ACS Journal of Surfaces and Colloids . 2020,第16期

机译：从尿道型层状钛酸盐纳米液中定制了特定刻面的TiO2纳米晶体的水热合成：系统调查和增强的光催化性能
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机译：四烷基铵盐对钛酸盐纳米液合成及反应性的系统评价
5. Hydrothermal synthesis and (Reactive) Templated Growth of sodium bismuth titanate. [D] . Nergiz, Saide Zeynep. 2009

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7. Tailored Hydrothermal Synthesis of Specific Facet-Dominated TiO2 Nanocrystals from Lepidocrocite-Type Layered Titanate Nanosheets: Systematical Investigation and Enhanced Photocatalytic Performance [O] . -1

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机译：仿生催化剂在活性金属氧化物纳米网络合成中的系统研究。

Systematic evaluation of tetraalkylammonium salts on the synthesis and reactivity of titanate nanosheets

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