Micro-Columnar Crystals with (-O=V-Pd-)_n Infinite Chain Structures Assembled by Hetero-Dinuclear Metal Complexes

机译：具有（-O = V-PD - ）_ n无限链结构的微柱状晶体（-O = V-PD - ）杂交链结构

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The inorganic and organic hybrid compound, [O=VPd(2-Pyd~-)_4]_n (2-Pyd~- = 2-pyridonate) (1), was synthesized by assembling its monomer units in the organic solution. X-ray absorption spectroscopic (XAFS) studies indicated that oxidation states of the vanadium and palladium ions in 1 were +IV and +11, and the distance between them was estimated to be 2.698-2.700 A. Scanning electron microscope (SEM) observation revealed that the compound 1 shapes in long columnar crystals with micrometer-sized cross section. EXAFS and IR studies suggested that the O=V oxygen atom interacted to the central palladium ion in the neighboring monomer unit, forming the inorganic infinite chain structure, -(O=V-Pd)_(n~-), in the columnar crystals of 1.

机译：通过在有机溶液中组装其单体单元，合成无机和有机杂化化合物[O = VPD（2-PYD〜 - ）_ 4] _N（2-PYD〜= 2-吡啶酸盐）（1）。 X射线吸收光谱（XAF）研究表明，钒和钯离子的氧化态在1中为+ IV和+11，并且它们之间的距离估计为2.698-2.700A。扫描电子显微镜（SEM）观察显示该化合物1以长柱状晶体形状，具有微米尺寸的横截面。 EXAFS和IR研究表明，O = V氧原子在相邻单体单元中与中央钯离子相互作用，形成无机无限链结构， - （O = V-PD）_（n〜 - ），柱状晶体1。

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《Asian International Conference on Advanced Materials》|2006年||共4页
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Y. Funahashi; T. Kamimura; M. Mizutani; Y. Wasada-Tsutsui; M. Sakai; H. Yashiro; T. Ozawa; K. Jitsukawa; H. Masuda;
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中图分类 TB3-53;
关键词
Inorganic/organic hybrid compound; Long columnar crystals; Linear chain structure;

机译：无机/有机杂化化合物;长柱状晶体;线性链结构;

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Micro-Columnar Crystals with (-O=V-Pd-)_n Infinite Chain Structures Assembled by Hetero-Dinuclear Metal Complexes

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