Manifestation of Fermi resonance in Raman spectra of micellar aqueous solutions of sodium octanoate

机译：辛酸钠水溶液Raman光谱中Fermi共振的表现

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The paper presents the results of an experimental study of the role of the Fermi resonance (FR) between the overtone of the bending and symmetric valence vibrations of the water molecule in micellar solutions of sodium octanoate in the mechanisms of formation of the water valence band. The analysis of broad spectral bands was carried out using genetic algorithms and gradient methods. The frequency detuning between the components of the Fermi-doublet for all the samples were obtained at room temperature. For aqueous solutions of sodium octanoate in the critical concentration of micelle formation (0.4 M) frequency detuning ceases to decrease with the growth of surfactant concentration, which is explained by the strengthening of the network of hydrogen bonds in the solution in the process of combining monomers and dimers of surfactants in multimolecular aggregates - micelles. A significant contribution of the Fermi resonance to the intensity of the valence band of water in sodium octanoate solutions was demonstrated. The FR interaction constants were calculated.

机译：本文介绍了FERMI共振（FR）在辛酸钠溶液溶液中水分子的弯曲和对称价振动的泛孔之间作用的实验研究的实验研究。使用遗传算法和梯度方法进行广谱带的分析。在室温下获得所有样品Fermi-Doublet的组分之间的频率静脉。对于胶质酸钠水溶液，在胶束形成的临界浓度（0.4M）的频率静脉中，随着表面活性剂浓度的生长，通过加强单体中的溶液中的氢键网络的加强来解释。多分子聚集体中表面活性剂的二聚体 - 胶束。证明了FERMI共振对辛酸钠溶液中水的价带强度的显着贡献。计算FR相互作用常数。

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《Saratov Fall Meeting;SPIE Conference on Laser Physics, Photonic Technologies, and Molecular Modeling;International Symposium on Optics and Biophotonics》|2020年|1 v. (various pagings) :|共8页
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I. V. Plastinin; S. A. Burikov; T. A. Dolenko; S. A. Dolenko;
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中图分类 N-532;
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Fermi resonance; Raman spectra; water; sodium octanoate; micelle; hydrogen bonds;

机译：费米共振;拉曼光谱;水;辛酸钠;胶束;氢键;

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专利

1. The Role of Fermi and Darling–Dennison Resonances in the Formation of the Raman Spectra of Water and Water–Ethanol Solutions [J] . I. V. Plastinin, S. A. Burikov, S. A. Dolenko, Bulletin of the Russian Academy of Sciences. Physics . 2019,第3期

机译：Fermi和Darling-Dennison共度在水和水 - 乙醇溶液中拉曼光谱形成中的作用
2. Contribution of Fermi and Darling–Dennison resonances to the formation of Raman spectra of water and water–ethanol solutions [J] . Plastinin I. V., Burikov S. A., Dolenko S. A., Journal of Raman Spectroscopy: An International Journal for Original Work in All Aspects of Raman Spectroscopy, Including Higher Order Processes, and Also Brillouin- and Rayleigh Scattering . 2017,第9期

机译：Fermi和Darling-Dennison共度对水和水 - 乙醇溶液拉曼光谱的贡献
3. Manifestation of hydrogen bonds of aqueous ethanol solutions in the Raman scattering spectra [J] . Dolenko T.A., Burikov S.A., Patsaeva S.V., Quantum electronics . 2011,第3期

机译：拉曼散射光谱中乙醇水溶液氢键的表现
4. Manifestation of Fermi resonance in Raman spectra of micellar aqueous solutions of sodium octanoate [C] . I. V. Plastinin, S. A. Burikov, T. A. Dolenko, Saratov Fall Meeting;SPIE Conference on Laser Physics, Photonic Technologies, and Molecular Modeling;International Symposium on Optics and Biophotonics . 2020

机译：辛酸钠水溶液Raman光谱中Fermi共振的表现
5. Oxidation of Organic Substrates in Aqueous Micellar Media Synthesis, Characterization and Application of N-alkyliminodiacetato Compounds for the Oxidation of Phenol and Carbon-Carbon Coupling of 2,6-di-tert-butylphenol in Aqueous Micellar Solutions. [D] . Cull, John Eli William. 2012

机译：胶束水溶液中有机底物的氧化胶束水溶液中2,6-二叔丁基苯酚的苯酚氧化和碳-碳偶联的N-烷基亚氨基二乙酰基化合物的合成，表征和应用。
6. Coherent anti-Stokes Raman scattering (CARS) spectra, with resonance enhancement, of cytochrome c and vitamin B12 in dilute aqueous solution. [O] . J Nestor, T G Spiro, G Klauminzer 2017

机译：稀水溶液中细胞色素c和维生素B12的相干抗斯托克斯拉曼散射（CARS）光谱具有共振增强作用。
7. Mixed Micellar Properties of Sodium n-Octanoate(SOC) with n-Octylammonium Chloride(OAC) in Aqueous Solution [O] . Byeong Hwan Lee 2002

机译：水溶液中N-辛基氯化铵（OC）与正辛酸钠（SoC）的混合胶束性质
8. Manifestation of the Fermi Resonance in Surface Polariton Spectra [R] . Puchkovskaya, G. A., Strizhevskiy, V. L., Frolkov, Y. A., 1984

机译：表面极化光谱中费米共振的表现

Manifestation of Fermi resonance in Raman spectra of micellar aqueous solutions of sodium octanoate

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