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Platinum reforming catalysts based on Zr-modified Al_2O_3 as support

机译:基于Zr改性的Al_2O_3作为支撑铂改造催化剂

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The formation of surface defects in γ-Al_2O_3 obtained by pseudoboehmite calcination and plasticized with oxalic acids is reported. Physicochemical properties of the Pt-containing catalysts based on unpromoted and zirconium-promoted alumina were compared with their catalytic activity in dehydrocyclization of n-heptane. The introduction of Zr in the Pt/Al_2O_3 catalyst was shown to decrease the helium pycnometer density of alumina and Zr locates in defect sites of alumina. The catalyst selectivity increased with the introduction of zirconium.
机译:据报道,据报道了通过假硼矿煅烧获得的γ-Al_2O_3和用草酸塑化的表面缺陷的形成。 将基于未氧化锆促进的氧化铝的含Pt的催化剂的物理化学性质与其脱水循环化的正庚烷催化活性进行比较。 在Pt / Al_2O_3催化剂中引入Zr在氧化铝的缺陷位点中降低氧化铝和Zr的氦气计密度。 催化剂选择性随着锆的引入而增加。

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