Mild Synthesis of Cyclohexanol and Cyclohexanone Via Electrocatalytic Reduction of Phenols Using Dispersed Metal Catalysts

机译：通过使用分散的金属催化剂通过电催化还原酚通过电催化还原的环己醇和环己酮的含量

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Cyclohexanol and cyclohexanone are industrially important chemicals for the synthesis of Nylon polymers. On the industrial scale, they are produced by thermocatalytic processes, either phenol hydrogenation (140-170°C, 1 atm) or cyclohexane oxidation (140-180°C, 0.8-2 MPa), which require high temperatures and external gas supply. This work demonstrates that electrosynthesis of cyclohexanol and cyclohexanone can be done at mild conditions using diverse aqueous electrolytes and dispersed metal catalysts (Pt/C, Ru/C, and Pd/C).

机译：环己醇和环己酮是工业上重要的化学品，用于合成尼龙聚合物。在工业规模上，它们是通过热催化过程生产的，苯酚氢化（140-170℃，1atm）或环己烷氧化（140-180℃，0.8-2MPa），这需要高温和外部气体供应。该工作表明，使用各种水性电解质和分散的金属催化剂（Pt / C，Ru / C和Pd / C），可以在温和条件下进行环己醇和环己酮的电合成。

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《Pacific Rim Meeting on Electrochemical and Solid-State Science》|2020年|1761-2200p|共1页
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Yanuar Philip Wijaya; Kevin J. Smith; Chang Soo Kim; Elod Gyenge;
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1. Selective Synthesis of Cyclohexanol Intermediates from Lignin-Based Phenolics and Diaryl Ethers using Hydrogen over Supported Metal Catalysts: A Critical Review [J] . Gundekari Sreedhar, Karmee Sanjib Kumar Catalysis Surveys From Asia . 2021,第1期

机译：使用氢负载金属催化剂的基于木质素基酚类和二芳基醚的环己醇中间体的选择性合成：临界评论
2. Correction to: Selective Synthesis of Cyclohexanol Intermediates from Lignin-Based Phenolics and Diaryl Ethers using Hydrogen over Supported Metal Catalysts: A Critical Review [J] . Gundekari Sreedhar, Karmee Sanjib Kumar Catalysis Surveys From Asia . 2021,第1期

机译：校正：使用氢在负载金属催化剂上使用氢气选择基于木质素的酚类和二芳基醚的环己醇中间体的选择性：临界评论
3. Citric acid assisted one-step synthesis of highly dispersed metallic Co/SiO2 without further reduction: As-prepared Co/SiO2 catalysts for Fischer-Tropsch synthesis [J] . Lei Shi, Chunyang Zeng, Qihang Lin Catalysis Today . 2014,第Null期

机译：柠檬酸辅助一步法合成高度分散的金属Co / SiO2，无需进一步还原：制备的费托合成Co / SiO2催化剂
4. Mild Synthesis of Cyclohexanol and Cyclohexanone Via Electrocatalytic Reduction of Phenols Using Dispersed Metal Catalysts [C] . Yanuar Philip Wijaya, Kevin J. Smith, Chang Soo Kim, Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：通过使用分散的金属催化剂通过电催化还原酚通过电催化还原的环己醇和环己酮的含量
5. Synthesis of Well Dispersed Supported Metal Catalysts by Strong Electrostatic Adsorption and Electroless Deposition. [D] . Tengco, John Meynard Macasero. 2016

机译：强静电吸附和化学沉积法合成分散良好的负载型金属催化剂。
6. Au–Pd alloy nanoparticles supported on layered double hydroxide for heterogeneously catalyzed aerobic oxidative dehydrogenation of cyclohexanols and cyclohexanones to phenols [O] . Xiongjie Jin, Kento Taniguchi, Kazuya Yamaguchi, 2016

机译：负载在层状双氢氧化物上的Au-Pd合金纳米颗粒用于环己醇和环己酮的多相催化好氧氧化脱氢成酚
7. Carbon‐Based Metal‐Free Catalysts for Electrocatalytic Reduction of Nitrogen for Synthesis of Ammonia at Ambient Conditions [O] . Shenlong Zhao, Xunyu Lu, Lianzhou Wang, 2019

机译：用于在环境条件下为氮气进行电催化还原氮气的碳基无金属催化剂

Mild Synthesis of Cyclohexanol and Cyclohexanone Via Electrocatalytic Reduction of Phenols Using Dispersed Metal Catalysts

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