ON THE REACTION OF NTO (3-NITRO-1,2,4-TRIAZOL-5-ONE) AND FOX-7 (1,1-DIAMINO-2,2-DINITROETHENE) WITH ALKYL ISOCYANATES

机译：在NTO（3-硝基-1,2,4-三唑-5-一）和福索-7（1,1-二氨基-2,2-二硝基乙烯）与烷基异氰酸酯的反应

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reactivity of the less-sensitive explosives NTO (3-nitro-1 ,2,4-triazol-5-one) and FOX-7 (1,1-diamino-2,2-dinitroethene) towards simple alkyl isocyanates was investigated. New carboxamidic derivatives have been synthesised by reacting the explosives with 1-isocyanatohexane (NTO and FOX-7) and 1,6-diisocyanato-hexane (NTO only) under relatively mild conditions. The new products were characterised by a combination of 1H and 13C NMR and FTIR spectroscopy, single crystal X-ray diffraction and differential scanning calorimetry.

机译：研究了较低敏感的炸药NTO（3-硝基-1,2,4-三唑-5-一）和FoX-7（1,1-二氨基-2,2-二硝基乙烯）的反应性，朝向简单的烷基异氰酸酯。通过在相对温和的条件下使爆炸物用1-异氰酸盐（NO和FOX-7）和1,6-二异氰酸盐 - 己烷（仅）反应，通过使爆炸物与相对温和的条件相对温和而合成了新的羧酰胺衍生物。新产品的特征在于1H和13C NMR和FTIR光谱，单晶X射线衍射和差示扫描量热法的组合。

著录项

来源
《Seminar on new trends in research of energetic materials》|2009年||共8页
会议地点
作者

展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类爆炸物工业、火柴工业;
关键词
NTO; FOX-7; 1-isocyanatohexane; 1,6-diisocyanatohexane; polyiso-cyanate-cured PBX;

机译：no;Fox-7;1-异氰酸盐;1,6-二异氰基己烷;聚异氰酸酯固化的PBX;

相似文献

外文文献
中文文献
专利

1. Transamination reactions of 1,1-diamino-2,2-dinitroethene (FOX-7) [J] . Bellamy AJ., Latypov NV., Goede P. Journal of Chemical Research. Synopses . 2002,第6期

机译：1,1-二氨基-2,2-二硝基乙烯（FOX-7）的氨基转移反应
2. 1,1-Diamino-2,2-dinitroethene (FOX-7) and 1-amino-1-hydrazino-2,2-dinitroethene (HFOX) as amphoteres: bases with strong acids [J] . Vo Thao T., Shreeve Jeanne M. Journal of Materials Chemistry, A. Materials for energy and sustainability . 2015,第16期

机译：两性1,1-二氨基-2,2-二硝基乙烯（FOX-7）和1-氨基-1-肼基-2,2-二硝基乙烯（HFOX）：强酸碱
3. THERMAL DECOMPOSITION OF Li(NTO) centre dot 2H_2O AND Na(NTO) centre dot H_2O (NTO=ANION OF 3-NITRO-1,2,4-TRIAZOL-5-ONE):KINETICS DERIVED FROM T-JUMP/FTIR SPECTROSCOPY [J] . Yuanhua SUN, Tonglai ZHANG, Jianguo ZHANG, Collection of Czechoslovak Chemical Communications . 2006,第1期

机译：Li（NTO）中心点2H_2O和Na（NTO）中心点H_2O（NTO = 3-硝基-1,2,4-三唑-5-酮的阴离子）的热分解：由T-JUMP / FTIR光谱得出
4. ON THE REACTION OF NTO (3-NITRO-1,2,4-TRIAZOL-5-ONE) AND FOX-7 (1,1-DIAMINO-2,2-DINITROETHENE) WITH ALKYL ISOCYANATES [C] . Anthony J. Bellamy, Alessandro E. Contini, Matthew R.G. Andrews Seminar on new trends in research of energetic materials;NTREM '09 . 2009

机译：NTO（3-硝基-1,2,4-三唑-5-酮）和FOX-7（1,1-二氨基-2,2-二异丁烯）与烷基异氰酸酯的反应
5. Community Analysis of 3-Amino-1,2,4-Triazol-5-One (ATO) and 3-Nitro-1,2,4-Triazol-5-One (NTO) Degrading Microbial Cultures [D] . ?Brooks, Matthew 2020

机译：群落分析 3- 氨基-1,2,4- 三唑 -5-酮（ATO）和 3-硝基 -1,2,4- 三唑 -5-酮（ NTO）降解的微生物培养
6. Biochemistry of protein-isocyanate interactions: a comparison of the effects of aryl vs. alkyl isocyanates. [O] . W E Brown, A H Green, T E Cedel, 1987

机译：蛋白质-异氰酸酯相互作用的生物化学：芳基和烷基异氰酸酯作用的比较。
7. Compatibility Study of 1,1-Diamino-2,2-Dinitroethene (FOX-7) with Some Energetic Materials [O] . Yuan-ping Zhang, Cong-hua Hou, Xin-lei Jia, 2020

机译：1,1氨基-2,2-二硝基乙烯（FOX-7）与一些能量材料的相容性研究

ON THE REACTION OF NTO (3-NITRO-1,2,4-TRIAZOL-5-ONE) AND FOX-7 (1,1-DIAMINO-2,2-DINITROETHENE) WITH ALKYL ISOCYANATES

摘要

著录项

相似文献

相关主题

期刊订阅