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Characterization of polymer, DNA-based and silk thin film resistivities and of DNA-based films prepared for enhanced electrical conductivity

机译:表征聚合物,基于DNA和丝绸的薄膜电阻率以及为增强电导率而准备的基于DNA的薄膜

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DC resistivity studies were carried out on biopolymer films of DNA-CTMA and silk fibroin, and on selected traditional polymer films, including PMMA and APC. Films of DNA-CTMA versus molecular weight and with conductive dopants PCBM, BAYTRON P and ammonium tetrachloroplatinate are reported. The films were spin coated on glass slides configured for measurements of volume dc resistance. The measurements used the alternating polarity method to record the applied voltage-dependent current independent of charging and background currents. The Arrhenius equation plus a constant was fitted to the conductivity versus temperature data of the polymers and the non-doped DNA-based biopolymers with activation energies ranging from 0.8 to 1.4 eV.
机译:在DNA-CTMA和丝素蛋白的生物聚合物薄膜以及包括PMMA和APC在内的某些传统聚合物薄膜上进行了直流电阻率研究。据报道,DNA-CTMA膜相对于分子量,并带有导电掺杂剂PCBM,BAYTRON P和四氯铂酸铵。将薄膜旋涂在载玻片上,该载玻片用于测量体积直流电阻。测量使用交替极性方法来记录所施加的电压相关电流,而与充电电流和背景电流无关。将Arrhenius方程加一个常数拟合到活化能范围为0.8到1.4 eV的聚合物和非掺杂的基于DNA的生物聚合物的电导率与温度数据之间。

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