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First-order Judd-Ofelt optical characterization of DNA-Ln(3+) complexes

机译:DNA-Ln(3+)配合物的一阶Judd-Ofelt光学表征

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摘要

Complexes formed of deoxyribose nucleic acid (DNA) and trivalent lanthanide ions (Ln~(3+)) promise a combination of high optical gain and low optical loss in an organic polymer host matrix. However, there has been some dispute about the binding mechanism between the DNA helix and the positively-charged lanthanide ions. Here we introduce an attempt to resolve the mechanism for binding through Judd-Ofelt analysis on DNA-Eu~(3+), DNA-Tb~(3+), and DNA-Sm~(3+) to first order. From initial Judd-Ofelt parameters extrapolations can be made to the line strengths, Einstein coefficients, and fluorescence lifetimes.
机译:由脱氧核糖核酸(DNA)和三价镧系离子(Ln〜(3+))形成的复合物有望在有机聚合物基质中实现高光学增益和低光学损失的组合。然而,关于DNA螺旋与带正电的镧系元素离子之间的结合机制存在一些争议。在这里,我们介绍了一种尝试,通过对DNA-Eu〜(3 +),DNA-Tb〜(3+)和DNA-Sm〜(3+)进行Judd-Ofelt分析来解决结合机理。从最初的Judd-Ofelt参数可以推断出线强度,爱因斯坦系数和荧光寿命。

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