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NATURALLY PRODUCED ANATASE NANOSTRUCTURED FILMS DURING THE HYDROTHERMAL ALTERATION OF BIOTITE

机译:水热石蜡热交替过程中天然产生的锐钛矿纳米结构膜

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Hydrothermally altered volcanic rocks extended over an area of about 1 km~2 in the Southwestern part of Limnos, island, Northeast Aegean sea, Greece, were found and studied using XRPD, SEM, SEM-EDS and FT-Raman techniques. The alteration of the parent rocks resulted from the circulation of hydrothermal fluids through faults and fractures. Mineralogical data indicate that the temperature prevailed during the hydrothermal alterations were about 80-100 ℃.rnAnatase is mainly the alteration product of ilmenite. The layer structure of micas, especially biotite, seems to be the main factor controlling the morphology of the newly formed anatase. Anatase nanoparticles are found between and on micas layers. With increasing alteration anatase nanostructured films are formed which are parallel to mica layers. Preliminary experimental studies, on mixtures of biotite and anatase at 95 ℃ and various pH values showed that the formation of anatase nanostructured films between biotite layers in the laboratory is possible and that during this nanofabrication a small part of biotite can be transformed to anatase pillared mica, depending on the pH. Hydrothermally altered volcanic rocks extended over an area of about 1 km2 in the Southwestern part of Limnos, island, Northeast Aegean sea, Greece, were found and studied using XRPD, SEM, SEM-EDS and FT-Raman techniques. The alteration of the parent rocks resulted from the circulation of hydrothermal fluids through faults and fractures. Mineralogical data indicate that the temperature prevailed during the hydrothermal alterations were about 80-100 ℃.
机译:利用XRPD,SEM,SEM-EDS和FT-Raman技术对希腊林姆诺斯岛西南部,岛屿爱琴海东南部约1 km〜2的热液蚀变火山岩进行了研究。母岩的变化是由于热液通过断层和裂缝的循环而引起的。矿物学资料表明,热液蚀变过程中的温度普遍在80-100℃左右。锐钛矿主要是钛铁矿的蚀变产物。云母,尤其是黑云母的层状结构似乎是控制新形成的锐钛矿形态的主要因素。在云母层之间和之上发现了锐钛矿纳米颗粒。随着变化的增加,形成了与云母层平行的锐钛矿型纳米结构膜。初步实验研究了在95℃和不同pH值下黑云母和锐钛矿的混合物,表明在实验室中黑云母层之间可以形成锐钛矿纳米结构膜,并且在这种纳米加工过程中,一小部分黑云母可以转化为锐钛矿柱状云母。 ,具体取决于pH值。利用XRPD,SEM,SEM-EDS和FT-Raman技术研究并研究了在希腊利姆诺斯岛西南部爱琴海东北部约1 km2区域内热液蚀变的火山岩。母岩的变化是由于热液通过断层和裂缝的循环而引起的。矿物学资料表明,热液蚀变过程中的主要温度为80-100℃。

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