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Preparation and characterization of supported Pt nanoparticles for N2O-H2 reaction

机译:用于N 2 O-H 2 反应的负载型Pt纳米颗粒的制备与表征

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Highly dispersed Pt nanoparticles were prepared by exchanging H+ sites in surface OH groups present on porous SiO2 for [Pt(NH3)4]2+ ions in a solution and were characterized using various characterization techniques. The metallic Pt particles with three different coordination environments had very small sizes near 1 nm and were uniformly distributed on the support. These nanodispersed Pt particles gave high intrinsic activity in N2O-H2 reaction at very low temperatures, such as 363 K.
机译:通过将存在于多孔SiO 2 上的表面OH基中的H + 位置交换为[Pt(NH 3 4 ] 2 + 离子,并使用各种表征技术对其进行了表征。具有三种不同配位环境的金属Pt颗粒在1 nm附近的尺寸很小,并且均匀分布在载体上。这些纳米分散的Pt颗粒在非常低的温度(例如363 K)下的N 2 O-H 2 反应中具有很高的固有活性。

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