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STUDY OF NANOSTRUCTURED Cu-FERROSPINEL FOR MAGNETIC STORAGE MEDIA

机译:磁性存储介质的纳米结构铜铁锰合金的研究

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Ferrospinel oxide powders were obtained by co-precipitation in alkaline medium of Fe~(3+)and Cu~(2+) cations from water solutions of chlorides of these elements. Two kinds of Cu-spinel powders were synthesized - cubic and tetragonal - depending on the Cu/Fe ratio in the solution. The size of the particles was about 6.5 nm. The Moessbauer analysis showed superparamagnetic properties for the two kinds of powders. The M(H) curves showed non-hysteretic behavior at room temperature, and different saturation magnetization and hysteresis loops at 4.2 K and high magnetic fields. The modified ferrite plating enabled us to produce Cu-ferrospinel films with cubic and tetragonal crystalline structure and to study Jahn-Teller distortion. The films with JT distortion showed coercivities of 900 Oe.
机译:通过在碱性介质中从这些元素的氯化物水溶液中共沉淀Fe〜(3+)和Cu〜(2+)阳离子获得氧化铁亚铁粉。根据溶液中的铜/铁比,合成了两种Cu-spinel粉末(立方和四方)。颗粒的尺寸为约6.5nm。 Moessbauer分析显示两种粉末的超顺磁性。 M(H)曲线在室温下显示出非磁滞行为,并且在4.2 K和高磁场下具有不同的饱和磁化强度和磁滞回线。改性的铁素体镀层使我们能够生产具有立方和四方晶体结构的Cu-ferrospinel膜并研究Jahn-Teller畸变。具有JT畸变的膜显示出900 Oe的矫顽力。

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