CATALYTIC ASYMMETRIC SYNTHESIS WITH NOVEL MONODENTATE PHOSPHORUS LIGANDS

机译：新型单齿磷配位体的催化不对称合成

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A library of new fine-tunable monodentate phosphite and phosphoramidite ligands based on chiral biphenol has been designed and developed. These monodentate phosphorus ligands have exhibited excellent enantioselectivity in the Pd-catalyzed asymmetric allylic alkylation, Rh-catalyzed asymmetric hydrogenation and hydroformylation, and Cu-catalyzed conjugate addition reactions.

机译：已经设计和开发了基于手性双酚的新型可微调单齿亚磷酸酯和亚磷酰胺配体的库。这些单齿磷配体在Pd催化的不对称烯丙基烷基化反应，Rh催化的不对称氢化和加氢甲酰化反应以及Cu催化的共轭加成反应中表现出出色的对映选择性。

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来源
《NATO Advanced Study Institute on New Methodologies and Techniques for a Sustainable Organic Chemistry: Sustainable Development in a Secure Environment Certosa di Pontignano; 20051014-23; Siena(IT)》|2005年|P.2954|共2页
会议地点 Siena(IT)
作者
BRUNO D. CHAPSAL; IWAO OJIMA;
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作者单位

Department of Chemistry, State University of New York at Stony Brook, Stony Brook NY 11790-3400, USA;

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会议组织
原文格式 PDF
正文语种 eng
中图分类基本有机化学工业;
关键词
biphenol-based; monodentate; phosphorus; phosphoramidite asymmetric; catalysis; hydrogenation; allylic-alkylation; hydroformylation; conjugate-addition; enantioselectivity; regioselectivity; rhodium; palladium; copper;

机译：双酚基;单齿;磷;亚磷酰胺不对称;催化;加氢;烯丙基烷基化;加氢甲酰化;共轭加成;对映选择性;区域选择性;铑;钯;铜;

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专利

1. Recent advances in catalytic asymmetric hydrogenation: Renaissance of the monodentate phosphorus ligands [J] . QUO Hongchao, DING Kuiling, DAI Lixin Chinese science bulletin . 2004,第19期

机译：催化不对称加氢的最新进展：单齿磷配体的复兴
2. Recent advances in catalytic asymmetric hydrogenation: Renaissance of the monodentate phosphorus ligands [J] . QUO Hongchao, DING Kuiling, DAI Lixin Chinese science bulletin . 2004,第19期

机译：催化不对称加氢的最新进展：单齿磷配体的复兴
3. Synthesis of New Chiral Monodentate Phosphite Ligands and Their Use in Catalytic Asymmetric Hydrogenation [J] . Zihao Hua, Victor C. Vassar, Iwao Ojima Organic letters . 2003,第21期

机译：新型手性单齿亚磷酸酯配体的合成及其在催化不对称加氢中的应用
4. Catalytic Asymmetric Synthesis With Novel Monodentate Phosphorus Ligands [C] . Bruno D. Chapsal, Iwao Ojima NATO Advanced Study Institute on New Methodologies and Techniques for a Sustainable Organic Chemistry: Sustainable Development in a Secure Environment Certosa di Pontignano . 2008

机译：具有新型单常磷配体的催化不对称合成
5. (I) Synthesis and Application of Chiral Biphenol-Based Phosphorus Ligands to Catalytic Asymmetric Synthesis; (II) Rhodium-Catalyzed Cycloaddition Reactions for Rapid Construction of Polycyclic Skeletons of Biological Interest [D] . Chien, Chih-Wei 2013

机译：（I）手性双酚基磷配体的合成及其在催化不对称合成中的应用；（II）铑催化的环加成反应快速构建具有生物意义的多环骨架
6. Asymmetric Catalysis Special Feature Part I: New biphenol-based fine-tunable monodentate phosphoramidite ligands for catalytic asymmetric transformations [O] . Zihao Hua, Victor C. Vassar, Hojae Choi, 2004

机译：不对称催化的特殊功能（第一部分）：用于催化不对称转化的新型双酚基可微调的单齿亚磷酰胺配体
7. Improved catalytic asymmetric carbon-carbon bond formation using combinations of chiral and achiral monodentate ligands [O] . Duursma A, Pena D, Minnaard AJ, 2005

机译：使用手性和非手性单齿配体的组合可改善催化不对称碳-碳键的形成

CATALYTIC ASYMMETRIC SYNTHESIS WITH NOVEL MONODENTATE PHOSPHORUS LIGANDS

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