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Electroabsorption of metallophthalocyanines

机译:金属酞菁的电吸收

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Abstract: Electroabsorption spectra have been measured on poly(methyl methacrylate) thin films doped with three kinds of metallophthalocyanines: tetrakis (tert-butyl) metal-free and lead phthalocyanines, and hexadeca (trifluoroethoxy) metal-free phthalocyanine. The third-order nonlinear optical susceptibility, $Chi$+(3)$/ ($MIN approximately ega@; approximately ega@, O, O), was determined from the electric field-induced absorption change. The considerable differences in absorption, electroabsorption, and complex $Chi$+(3)$/ ($MIN approximately ega@; approximately ega@, O, O) spectral profiles of these metallophthalocyanines are attributable to the difference in molecular aggregation states. !12
机译:摘要:在掺有三种金属酞菁的聚甲基丙烯酸甲酯薄膜上测量了电吸收光谱,该薄膜不含四(叔丁基)金属和铅酞菁,以及不含十六烷基(三氟乙氧基)的金属酞菁。从电场引起的吸收变化确定三阶非线性光学磁化率$ Chi $ +(3)$ /($ MIN大约ega @;大约ega @,O,O)。这些金属酞菁在吸收,电吸收和复杂的$ Chi $ +(3)$ /($ MIN大约ega @;大约ega @,O,O)光谱分布上的显着差异可归因于分子聚集态的差异。 !12

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