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Photoinduced switching of electrical properties in thin films of polar indandione type organic molecules

机译:极性茚满二酮类有机分子薄膜中电学性质的光诱导转换

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The optically induced switching of organic materials with large dipole moments consisting of acceptor and donor groups bridged by a delocalized π-electron system is important for investigations of optoelectronic effects. To the contrary of azobenzene molecule, photoinduced change of dipole moment of indandione molecule does not need free volume in thin films. To modify the dipole moment and also to optimise properties of film formation, a number of novel indandione derivatives is investigated. Reversible switching of the surface potential of polymer films with incorporated or chemically attached indandione molecules is observed at irradiation in photoinduced intramolecular electron transfer wavelength.
机译:具有大偶极矩的有机材料的光诱导转换,由受局域π电子系统桥接的受主和施主基团组成,对光电效应的研究非常重要。与偶氮苯分子相反,茚满二酮分子的偶极矩的光诱导变化不需要薄膜中的自由体积。为了改变偶极矩并优化成膜性能,研究了许多新型茚满二酮衍生物。在光诱导的分子内电子转移波长的辐射下观察到具有并入或化学连接的茚满二酮分子的聚合物膜的表面电势的可逆转换。

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