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Modeling the Wet Spinning of Synthetic Fiber from Polymer Solutions

机译:从聚合物溶液模拟合成纤维的湿纺

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The study under review is devoted to a mathematical model of non-isothermal gel formation. This model includes the following: a diagram of the phase balance of the polymer-solvent-coagulant system, the heat transfer processes, the temperature dependence of the diffusion processes, the existence of the bi- phase layered structure and the change of the fibre size during the process. This model describes the process of chemical fiber wet spinning. Three gelation mechanisms of fibre spinning from polymer solutions are under discussion. They are diffusive, thermotropic, mechanotropic. We have constructed mathematical analytical models for the diffusive and thermotropical gel formation of jets from polymer solutions. The rule for the gel thickness in relation to time has been laid down and estimates of the characteristic time for the gel formation process in each separate mechanism have been obtained.
机译:审查中的研究致力于非等温凝胶形成的数学模型。该模型包括以下内容:聚合物-溶剂-凝结剂系统的相平衡图,传热过程,扩散过程的温度依赖性,双相层状结构的存在以及纤维尺寸的变化在此过程中。该模型描述了化学纤维湿法纺丝的过程。从聚合物溶液纺丝的三种胶凝机理正在讨论中。它们是扩散的,热致的,致力的。我们已经建立了用于从聚合物溶液中形成射流的扩散和热凝胶形成的数学分析模型。已经确定了相对于时间的凝胶厚度的规则,并且已经获得了在每个单独的机理中凝胶形成过程的特征时间的估计。

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