首页> 外文会议>Proceedings of the International Wire amp; Cable Symposium (IWCS~TM), Inc. >Performance comparison of Bio-based Plasticizers with selected phthalate and non-phthalate alternatives in Wire Cable Jacket application
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Performance comparison of Bio-based Plasticizers with selected phthalate and non-phthalate alternatives in Wire Cable Jacket application

机译:生物基增塑剂与精选邻苯二甲酸酯和非邻苯二甲酸酯替代品在电线和电缆护套应用中的性能比较

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摘要

Phthalate esters such as DOP, DINP, and DIDP are predominantly used in PVC Wire & Cable jacket applications. Of late, there is an increasing drive in the market place to find alternatives to these phthalates. Even though commercially available non- ortho phthalates such as dioctyl terephthalates (DOtP) and hydrogenated phthalates (Hexamol-DINCH) work in various PVC applications, our results show that they do not meet thermal heat aging requirements for most jacket applications except for the very low-temperature rated cable. The jacket properties of two different grades of DOW ECOLIBRIUM™ plasticizers, classified according to their performance in weight loss upon heat aging, are compared against the ortho-phthalates, non ortho-phthalates, and some other commercially available bio-based plasticizers. The critical comparative data that are collected include thermal stability for the compounds, shore hardness, unaged and aged tensile properties, plasticizer compatibility, low-temperature flexibility, and volume resistivity. The results show that between the two different DOW ECOLIBRIUM™ grades, it is possible to meet requirements for PVC jacket standards in various geographies.
机译:邻苯二甲酸酯(例如DOP,DINP和DIDP)主要用于PVC电线和电缆护套应用中。最近,在市场上寻找这些邻苯二甲酸酯的替代品的动力越来越强。即使市售的非邻苯二甲酸酯,例如对苯二甲酸二辛酯(DOtP)和氢化邻苯二甲酸酯(Hexamol-DINCH)可以在各种PVC应用中使用,我们的结果表明,除了非常低的用量外,它们还不能满足大多数外套应用的热老化要求额定温度的电缆。将两种不同等级的DOW ECOLIBRIUM™增塑剂的护套性能(根据其在热老化时的失重性能进行分类)与邻苯二甲酸酯,非邻苯二甲酸酯和其他一些市售生物基增塑剂进行比较。收集的关键比较数据包括化合物的热稳定性,肖氏硬度,未老化和老化的拉伸性能,增塑剂的相容性,低温柔韧性和体积电阻率。结果表明,在两种不同的DOW ECOLIBRIUM™牌号之间,可以满足不同地区对PVC护套标准的要求。

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