Rhodiun Complexes with Bident N-Heterocyclic Carbenes

机译：Rhodiun复合物与潜在的N-杂环卡宾

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Metal complexes of N-heterocyclic carbenes(NHCs)have attracted considerable attention in organometallic coordination chemistry,due to their successful application in homogeneous catalysis especially in C-C/C-N coupling reaction and olefin metatheses.Although a large number of transition-metal carbene complexes have been reported,investigations of rhodium complexes with bidentcarbeneligands have been limited so far[1-2].Herein we report our synthesis of rhodium complex with bident N-heterocyclic carbenes.

机译：由于N-杂环卡宾（NHCs）的金属配合物在均相催化中的成功应用，特别是在CC / CN偶联反应和烯烃复分解中的应用，在有机金属配位化学领域引起了广泛的关注。据报道，迄今为止，铑与双齿碳烯配体的配合物的研究还很有限[1-2]。在这里，我们报道了我们的双齿N-杂环卡宾与铑配合物的合成。

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来源
《Proceedings of the Sixth Asia-Europe symposium on processing and properties of reinforced polymers》|2013年|251|共1页
会议地点 Wuhan(CN)
作者
X.Y.Yu; X.G.Peng; Q.X.Zhang;
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作者单位

Institute of Polymer Science and Engineering, School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

Institute of Polymer Science and Engineering, School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

Institute of Polymer Science and Engineering, School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

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原文格式 PDF
正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Rhodium; Carbene; Heterocyclic; Complex;

机译：铑;卡宾;杂环;复杂;

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1. N-Propylphthalimide-Substituted Silver(I) N-Heterocyclic Carbene Complexes and Ruthenium(II) N-Heterocyclic Carbene Complexes: Synthesis and Transfer Hydrogenation of Ketones (vol 145, pg 631, 2015) [J] . Aktas Aydin, Gok Yetkin Catalysis Letters . 2016,第1期

机译：N-丙基邻苯二甲酰亚胺取代的银（I）N-杂环碳配合物和钌（II）N-杂环碳配合物：酮的合成和转移加氢（第145卷，第631页，2015年）
2. N-Propylphthalimide-Substituted Silver(I) N-Heterocyclic Carbene Complexes and Ruthenium(II) N-Heterocyclic Carbene Complexes: Synthesis and Transfer Hydrogenation of Ketones [J] . Aktas Aydin, Gok Yetkin Catalysis Letters . 2015,第2期

机译：N-丙基邻苯二甲酰亚胺取代的银（I）N-杂环碳配合物和钌（II）N-杂环碳配合物：酮的合成和转移加氢
3. A comparison between (a/n-NHC)PdX2(pyridine) and (a/n-NHC)(2)PdX2 (X=I, Cl) type complexes of abnormal fused-bicyclic imidazo[1,2-a] pyridine based N-heterocyclic carbene (a-NHC) and of normal imidazole based N-heterocyclic carbene (n-NHC) ligands in the Suzuki-Miyaura coupling reactions [J] . Modak Sudipta, Borah Suchibrata, Prakasham A. P., Inorganica Chimica Acta . 2019,第期

机译：（A / N-NHC）PDX2（吡啶）和（A / N-NHC）（2）PDX2（X = I，CL）异常熔融 - 双环咪唑的型复合物（A / N-NHC）和（A / N-NHC）（2）PDX2（X = I，CL）[1,2-A]吡啶基正杂胺基于苏苏 - 宫达偶联反应中的正杂环基石（A-NHC）和正常的咪唑基N-杂环（N-NHC）配体
4. Rhodiun Complexes with Bident N-Heterocyclic Carbenes [C] . X.Y.Yu, X.G.Peng, Q.X.Zhang Asia-Europe symposium on processing and properties . 2013

机译：罗达昆配合物与二岁的n-杂环carbenes
5. Novel N-heterocyclic dicarbene ligands and molybdenum and dimolybdenum N-heterocyclic carbene complexes [D] . Bemowski, Ross David 2013

机译：新型N杂环二卡宾配体以及钼和二钼N杂环卡宾配合物
6. From betaines to anionic N-heterocyclic carbenes. Borane gold rhodium and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer [O] . Ming Liu, Jan C Namyslo, Martin Nieger, 2016

机译：从甜菜碱到阴离子N-杂环卡宾。从咪唑酚盐及其卡宾互变异构体开始的硼烷金铑和镍络合物
7. From betaines to anionic N-heterocyclic carbenes. Borane, gold, rhodium, and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer [O] . Ming Liu, Jan C. Namyslo, Martin Nieger, 2016

机译：从甜菜碱到阴离子N-杂环卡宾。硼烷，金，铑和镍配合物，起始于咪唑啉酚及其卡宾互变异构体

Rhodiun Complexes with Bident N-Heterocyclic Carbenes

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