SYNTHESIS AND PROPERTIES OF OPEN-CAGE FULLERENE C_(70) DERIVATIVES

机译：开笼富勒烯C_（70）衍生物的合成及性质

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A novel open-cage fullerene C_(70) derivative having a 13-membered ring orifice was synthesized by the reaction of C_(70) with a pyridazine derivative, followed by photochemical oxidation and insertion of a sulfur atom to the orifice. The 100% encapsulation of molecular hydrogen was achieved by treatment of the open-cage C_(70) derivative with high-pressure hydrogen for the first time.

机译：通过使C_（70）与哒嗪衍生物反应，然后进行光化学氧化并将硫原子插入孔中，来合成具有13元环孔的新型开笼式富勒烯C_（70）衍生物。分子氢的100％包封是通过用高压氢首次处理开笼C_（70）衍生物来实现的。

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《Proceedings vol.2004-12; Electrochemical Society(ECS) Annual Spring Meeting and International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters; 20040509-13; San Antonio,TX(US)》|2004年|P.267-274|共8页
会议地点 San AntonioTX(US)
作者
Yasujiro Murata; Shuhei Maeda; Michihisa Murata; Koichi Komatsu;
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作者单位

Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan;

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原文格式 PDF
正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. Synthesis of the First Dihydrofuran Derivative of Fullerene C_(70), 4'-Acetyl-5'-methylfurano[2',3':7,8]- (C_(70)-D_(5h(6)))[5,6]fullerene by Reaction of C_(70) with VO(acac)2, MoO2(acac)2, and Ni(acac)2 [J] . R. G Bulgakov, Z. S. Kinzyabaeva Russian Journal of Organic Chemistry . 2013,第12期

机译：富勒烯C_（70），4'-乙酰基-5'-甲基呋喃[2'，3'：7,8]-（C_（70）-D_（5h（6）））[5的第一个二氢呋喃衍生物的合成，6] C_（70）与VO（acac）2，MoO2（acac）2和Ni（acac）2反应生成的富勒烯
2. Synthesis and Structure of an Open-Cage Thiafullerene C_(69)S: Reactivity Differences of an Open-Cage C_(70) Tetraketone Relative to Its C_(60) Analogue [J] . Rui Zhang, Tsukasa Futagoishi, Michihisa Murata, Journal of the American Chemical Society . 2014,第23期

机译：开笼式硫富勒烯C_（69）S的合成和结构：开笼式C_（70）四酮相对于其C_（60）类似物的反应性差异
3. Synthesis and optical properties of [C_(60)/C_(70)] fullerene derivatives containing spirobifluorene and imidazole units [J] . CHIHUA LI, HEPING ZENG, XINHUA OUYANG, Journal of optoelectronics and advanced materials . 2011,第3a4期

机译：含螺二芴和咪唑单元的[C_（60）/ C_（70）]富勒烯衍生物的合成及光学性质
4. SYNTHESIS AND PROPERTIES OF OPEN-CAGE FULLERENE C_(70) DERIVATIVES [C] . Yasujiro Murata, Shuhei Maeda, Micliihisa Murnta, Electrochemical Society Annual Meeting . 2005

机译：开放式富勒烯C_（70）衍生物的合成与性能
5. Fullerene carbon-70 derivatives dampen anaphylaxis and allergic asthma pathogenesis in mice. [D] . Norton, Sarah Brooke. 2012

机译：富勒烯碳70衍生物可抑制小鼠的过敏反应和过敏性哮喘发病机理。
6. Enhanced Open-Circuit Voltage in Perovskite Solar Cells with Open-Cage 60Fullerene Derivatives as Electron-Transporting Materials [O] . Edison Castro, Albert Artigas, Anna Pla-Quintana, 2019

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7. First synthesis of fullerene trimer C180 and its structural identification by scanning tunnelling microscopy(STM) / Synthesis of novel derivatives of fullerene dimers and open-cage fullerene (ORGANIC MATERIALS CHEMISTRY - High-Pressure Organic Chemistry) [O] . KOMATSI Koichi, KITAGAWA Toshikazu, MORI Sadayuki, 2002

机译：富勒烯三聚体C180的首次合成及其通过扫描隧道显微镜（STM）的结构鉴定/富勒烯二聚体和开笼式富勒烯新型衍生物的合成（有机材料化学-高压有机化学）
8. Studies of C60, C70 and Other Fullerenes: Synthesis, Derivatization,Electrochemistry, Lubricant Properties and New Composite Materials [R] . Smalley, R. E., Margrave, J. L., Hauge, R. H., 1995

机译：C60，C70和其他富勒烯的研究：合成，衍生化，电化学，润滑性能和新型复合材料

SYNTHESIS AND PROPERTIES OF OPEN-CAGE FULLERENE C_(70) DERIVATIVES

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