ELECTROCHEMICAL TRANSFORMATIONS OF C_(60) FULLERENE FILMS IN SOLUTIONS CONTAINING WATER

机译：C_（60）富勒烯薄膜在含水溶液中的电化学转变

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In this work we show that the electrochemical properties of fullerene films depend very much on their structures. Reversible electrochemical transformation of the films in dimethylformamide+water mixtures containing potassium ions, results in an opener structure which allows easier reduction. These rearranged films show much larger efficiency in photoelectrochemical measurements. Furthermore, this structural change provides the possibility to hydrogenate electrochemically C_(60) in solid state. The resulted H_xC_(60) was shown to be an n-type semiconductor with very large photoefficiency toward the oxidation of ascorbic acid.

机译：在这项工作中，我们证明了富勒烯薄膜的电化学性质在很大程度上取决于其结构。薄膜在含钾离子的二甲基甲酰胺+水混合物中的可逆电化学转变导致形成开放剂结构，该结构更易于还原。这些重新排列的薄膜在光电化学测量中显示出更高的效率。此外，这种结构变化提供了将固态的C_（60）电化学加氢的可能性。结果表明，H_xC_（60）是一种n型半导体，对抗坏血酸的氧化具有很高的光效率。

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《Proceedings vol.2004-12; Electrochemical Society(ECS) Annual Spring Meeting and International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters; 20040509-13; San Antonio,TX(US)》|2004年|P.39-45|共7页
会议地点 San AntonioTX(US)
作者
A. Szuecs; V. Budavari; M. Novak; J. B.Nagy;
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University of Szeged, H-6701 Szeged, P.O.Box 105, Hungary;

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正文语种 eng
中图分类无机高分子化合物（高聚物）;
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ELECTROCHEMICAL TRANSFORMATIONS OF C_(60) FULLERENE FILMS IN SOLUTIONS CONTAINING WATER

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