The Study of Cerium Tetrafluoride Vaporization by Knudsen Effusion Mass Spectrometry

机译：Knudsen扩散质谱法研究四氟化铈的汽化

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The evaporation and decomposition of cerium tetrafluoride CeF_4(s) at high temperatures were studied by means of Knudsen Effusion Mass Spectrometry (KEMS). The saturated vapor pressure over CeF_4(s) was determined by the isothermal evaporation of the sample from Pt Knudsen cell. The enthalpy of CeF_4(s) sublimation was calculated using the second and the third laws of thermodynamics.

机译：利用Knudsen扩散质谱法（KEMS）研究了四氟化铈CeF_4在高温下的蒸发和分解。通过等温蒸发来自Pt Knudsen池的样品来确定CeF_4上的饱和蒸气压。使用第二和第三热力学定律计算CeF_4（s）的升华焓。

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《Proceedings of the workshop on knudsen effusion mass spectrometry》|2012年|191-195|共5页
会议地点 Julich(DE)
作者
N. S. Chilingarov; I. M. Shlyapnikov; Z. Mazej; A. E. Moiseev; Ya. M. Shlyapnikov; I. V. Ishtubaev;
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Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119992, Russia;

Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119992, Russia,Department of Inorganic Chemistry and Technology, Institute 'Jozef Stefan', Ljubljana 1000, Slovenia;

Department of Inorganic Chemistry and Technology, Institute 'Jozef Stefan', Ljubljana 1000, Slovenia;

Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119992, Russia;

Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119992, Russia;

Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119992, Russia;

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The Study of Cerium Tetrafluoride Vaporization by Knudsen Effusion Mass Spectrometry

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