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Mesoscopic Patterning Induced by Co-deposition of C_(60) and Ni on the MgO(l00) Single Crystal

机译:C_(60)和Ni共沉积在MgO(100)单晶上引起的介观图案化

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We report on an unusual phenomenon of pattern formation in the mixture of Ni and C_(60) co-deposited on the single crystal of MgO(l00). Under certain deposition kinetics an array of periodic stripes was formed. The stripes consist of sub-half-micrometer Ni droplets (embedded in the complex Ni-C base) and encompassed with a polymerized C_(60) rind. The stripes are bound to the thin double-layer platform consisting of the epitaxial Ni and amorphous C (a-C) layers. During co-deposition the C_(60) molecules partly disintegrate and transform towards the a-C structures. Accumulation of a-C (immiscible with Ni) may induce thermodynamic instability in the system and trigger the process of spontaneous partitioning. As a principal mechanism of the stripe formation a sequential drift and co-ordinate release of the incited instability was proposed.
机译:我们报告了共沉积在MgO(100)单晶上的Ni和C_(60)的混合物中形成图案的异常现象。在某些沉积动力学下,形成了周期性条纹的阵列。这些条纹由半微米以下的镍小滴(嵌入在复杂的Ni-C碱中)组成,并被聚合的C_(60)皮包围。条带绑定到由外延Ni和非晶C(a-C)层组成的薄双层平台上。在共沉积过程中,C_(60)分子会部分分解并向a-C结构转化。 a-C(与Ni不混溶)的积累可能会引起系统中的热力学不稳定,并触发自发分配过程。作为条纹形成的主要机理,提出了引起不稳定性的顺序漂移和坐标释放。

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