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Massive Transformation in High Niobium Containing TiAl-Alloys

机译:高铌TiAl合金的大规模转变

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摘要

Massive transformation in high Nb bearing γ-TiAl-based alloys, Ti-45Al-7.5Nb and Ti-46Al-9Nb (at.%), and the thermal stability of the resulting microstructure were investigated. Using a quenching dilatometer, a nearly complete massive transformation in Ti-45Al-7.5Nb was found at about 1050℃ after annealing at 1305℃ for 10min and subsequent cooling with a rate of 55K/s. Higher starting temperatures and higher cooling rates lead to incomplete massive transformation and small transformed areas situated at the grain-boundary triple points of the parent α-grains are observed. By means of EBSD only in one case the same orientation of the close-packed planes of parent α-grains and of massively transformed γ_M-areas was observed. The thermal stability of the microstructure of massively transformed Ti-46Al-9Nb sheet material was tested by annealing samples for 1 hour between 400 and 1200℃. Above 800℃ a drop of hardness was measured and X-ray diffraction patterns show an increasing separation of (200)_γ and (002)_γ reflections as expected from a tetragonal γ-TiAl lattice. After annealing at 1100℃ α_2-phase segregates at grain boundaries and after 1200℃ α_2-lamellae appear insides the γ_M-grains parallel to all four {111}_γ-planes.
机译:研究了高Nb含量的γ-TiAl基合金Ti-45Al-7.5Nb和Ti-46Al-9Nb(原子%)的大规模转变以及所得组织的热稳定性。使用淬火膨胀计,在1305℃退火10分钟并随后以55K / s的速率冷却后,在1050℃附近发现了Ti-45Al-7.5Nb几乎完全的块状转变。较高的起始温度和较高的冷却速率导致不完全的大相变,并且观察到位于母体α晶粒的晶界三点处的小相变区域。仅在一种情况下,通过EBSD观察到了母体α颗粒和大量转变的γ_M区域的密堆积平面的相同方向。通过在400℃至1200℃之间将样品退火1小时,测试了大相变Ti-46Al-9Nb片材的显微组织的热稳定性。在800℃以上,测得硬度下降,并且X射线衍射图显示(200)_γ和(002)_γ反射与四边形γ-TiAl晶格的间距越来越大。在1100℃退火后,α_2相在晶界偏析;在1200℃退火后,α_2层出现在平行于所有四个{111}_γ平面的γ_M晶粒内部。

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