A Novel Light-Emitting Mixed-Ligand Iridium(III) Complex With a Polymeric Terpyridine-PEG Macroligand: Synthesis And Characterization

机译：新型的带有聚合物联吡啶-PEG大配体的发光混合配体铱（III）配合物：合成与表征

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The synthesis of mixed ligand orthometalated iridium(III) complexes as well as the characterization of their electro-optical properties is briefly illustrated. The cyclic voltammetry results exemplify an enhanced stability of the complex with a poly(ethylene glycol (PEG) side chain compared to the corresponding organometallic model material. Less degradation of the electrically active centers was found to occur on the electrode surface. Furthermore the morphology of thin films of the described polymeric material was investigated with respect to potential applications in thin film devices.

机译：简要说明了混合配体原金属化铱（III）配合物的合成及其电光性质的表征。循环伏安法的结果表明，与相应的有机金属模型材料相比，带有聚乙二醇（PEG）侧链的配合物具有更高的稳定性，在电极表面上电活性中心的降解较少。就所描述的聚合物材料的薄膜在薄膜装置中的潜在应用进行了研究。

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《Symposium Proceedings vol.846; Symposium on Organic and Nanocomposite Optical Materials; 20041128-1203; Boston,MA(US)》|2004年|P.295-300|共6页
会议地点 BostonMA(US)
作者
Elisabeth Holder; Veronica Marin; Michael A. R. Meier; Dmitry Kozodaev; Ulrich S. Schubert;
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Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology and Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands;

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正文语种 eng
中图分类材料;
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专利

1. Iridium(III) complexes with PEO and PS polymer macroligands and light-emitting properties: Synthesis and characterization [J] . Holder E, Marin V, Kozodaev D, Macromolecular chemistry and physics . 2005,第10期

机译：具有PEO和PS聚合物大配体的铱（III）配合物和发光性能：合成与表征
2. A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly (ethylene glycol) macroligand [J] . Holder E, Marin V, Meier MAR, Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 2004,第16期

机译：一种新型发光混合配体铱（III）与三联吡啶-聚乙二醇大配体
3. Random Copolymers with Pendant Cationic Mixed-Ligand Terpyridine-Based Iridium (III) Complexes: Synthesis and Application in Light-Emitting Devices [J] . Frédéric Dumur, Yohann Guillaneuf, Audrey Guerlin, Macromolecular Chemistry and Physics . 2011,第15期

机译：悬垂阳离子混合配体基于吡啶的铱（III）配合物的无规共聚物：合成及在发光器件中的应用
4. Synthesis and Characterization of a Novel Organic Phosphorescent Iridium(III) Complex [C] . J. HUANG, Y. D. JIANG, X. Z. TANG, International Symposium on the Physical and Failure Analysis of Integrated Circuits . 2009

机译：新型有机磷光铱（III）复合物的合成与表征
5. Tris(guanidinato) complexes of iridium and rhodium in the oxidation states +III and +IV: Synthesis, characterization, and reactivity [D] . Lee, Wei-Tsung 2011

机译：氧化态+ III和+ IV的铱和铑的Tris（guanidinato）配合物：合成，表征和反应性
6. A Novel Polymethyl Methacrylate Derivative Grafted with Cationic Iridium(III) Complex Units: Synthesis and Application in White Light-Emitting Diodes [O] . Huaijun Tang, Xueyan Dong, Mingxian Chen, 2019

机译：阳离子铱（III）络合单元接枝的新型聚甲基丙烯酸甲酯衍生物：合成及在白光发光二极管中的应用
7. Cationic iridium(III) complexes bearing ancillary 2,5-dipyridyl(pyrazine) (2,5-dpp) and 2,2 ':5 ',2 ''-terpyridine (2,5-tpy) ligands : synthesis, optoelectronic characterization and light-emitting electrochemical cells [O] . Hasan, Kamrul, Donato, Loic, Shen, Yulong, 2014

机译：带有辅助2,5-二吡啶基（吡嗪）（2,5-dpp）和2,2'：5'，2''-吡啶（2,5-tpy）配体的阳离子铱（III）配合物：合成，光电表征和发光电化学电池

A Novel Light-Emitting Mixed-Ligand Iridium(III) Complex With a Polymeric Terpyridine-PEG Macroligand: Synthesis And Characterization

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