Bismuth as a semimetal is not a good thermoelectric material in bulk form because of the approximate cancellation between the electron and hole contributions. However, quantum confinement can be introduced by making Bi nanowires to move the lowest conduction suband edge up and the highest valence subband edge down to get a one-dimensional (1D) semiconductor at some critical wire diameter D_c. A theoretical model based on the basic band structure of bulk Bi is developed to predict the dependence of these quantities on wire diameter and on the crystalline orientation of the bismuth nanowires. Numerical modeling is performed for trigonal, binary and bisectrix crystal orientations. By carefully tailoring the Bi wire diameter a nd carrier concentration, substantial enhancement in the thermoelectric figure of merit is expected for small nanowire diameters.
展开▼
