BENZOIN CONDENSATION IN IONIC LIQUIDS VIA ELECTROCHEMICAL GENERATION OF CARBENE

机译：通过碳的电化学生成，离子液体中的苯甲酰缩合

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Herein we report the use of iV-Heterocyclic carbenes, generated by electrolysis, as organocatalysts in the benzoin condensation reaction. The effect of various electrochemical and physical parameters was studied, and the procedure was carried out using various aromatic, and heteroaromatic aldehydes. The use of classical solvents as well as any addition of bases was avoided.

机译：在本文中，我们报告了通过电解产生的iV-杂环卡宾在苯偶姻缩合反应中作为有机催化剂的用途。研究了各种电化学和物理参数的影响，并使用各种芳族和杂芳族醛进行了该过程。避免使用经典溶剂以及任何碱的添加。

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《Synthetic and mechanistic organic electron transfer reactions》|2009年|p.13-18|共6页
会议地点 Vienna(AT);Vienna(AT)
作者
I. Chiarotto; M. Feroci; M. Orsini; G. Sotgiu; L. Rossi;
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作者单位

Dip. Ingegneria Chimica, Materiali, Materie Prime, e Metallurgia, Universita "La Sapienza", via Castro Laurenziano, 7,1-00161 Roma, Italy;

Dip. Ingegneria Chimica, Materiali, Materie Prime, e Metallurgia, Universita "La Sapienza", via Castro Laurenziano, 7,1-00161 Roma, Italy;

Dip. Elettronica Applicata, Universita di Roma Tre, via VascaNavale 84,1-00146 Roma, Italy;

Dip. Elettronica Applicata, Universita di Roma Tre, via VascaNavale 84,1-00146 Roma, Italy;

Dip. Chimica, Ingegneria Chimica e Materiali, Universita degli Studi, Monteluco di Roio, 1-67040 L'Aquila, Italy;

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正文语种 eng
中图分类生物医学工程;
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专利

1. Benzoin condensation in 1,3-dialkylimidazolium ionic liquids via electrochemical generation of N-heterocyclic carbene [J] . Monica Orsini, Isabella Chiarotto, Mikhail N. Elinson, Electrochemistry communications . 2009,第5期

机译：通过N-杂环卡宾的电化学反应生成1,3-二烷基咪唑鎓离子液体中的苯偶姻缩合
2. Study on the Reactivity of Aldehydes in Electrolyzed Ionic Liquids: Benzoin Condensation - Volatile Organic Compounds (VOCs) vs. Room Temperature Ionic Liquids (RTILs) [J] . I. Chiarotto, M. Feroci, M. Orsini Advanced synthesis & catalysis . 2010,第18期

机译：电解离子液体中醛的反应性研究：安息香缩合-挥发性有机化合物（VOC）与室温离子液体（RTIL）
3. Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation [J] . Audrey Aupoix, Bruce Pegot, Giang Vo-Thanh Tetrahedron . 2010,第6期

机译：咪唑鎓和吡啶鎓类离子液体的合成以及使用1-烷基-3-甲基咪唑鎓盐作为无溶剂和微波活化的安息香缩合的预催化剂的应用
4. BENZOIN CONDENSATION IN IONIC LIQUIDS VIA ELECTROCHEMICAL GENERATION OF CARBENE [C] . I. Chiarotto, M. Feroci, M. Orsini, Symposium on synthetic and mechanistic organic electron transfer reactions . 2010

机译：通过电化学产生Carbene的离子液体中的苯并凝结
5. Sum frequency generation and electrochemical studies of ionic liquid interfaces. [D] . Aliaga, Cesar. 2007

机译：总频率生成和离子液体界面的电化学研究。
6. Molecular-Level Investigation of Cycloaliphatic Epoxidised Ionic Liquids as a New Generation of Monomers for Versatile Poly(Ionic Liquids) [O] . Baris Demir, Gabriel Perli, Kit-Ying Chan, 2021

机译：脂环族环氧化离子液体作为新一代单体的多种单体进行含量（离子液体）
7. Thiazolium and imidazolium cations from ionic liquids as pre-catalysts in benzoin condensation–a mini review [O] . Juan Manuel Urbina-González, Andrés Felipe Villamizar-Mogotocoro 2018

机译：来自离子液体的噻唑鎓和Imidazolium阳离子作为苯并蛋白缩合的催化剂 - 迷你评论

BENZOIN CONDENSATION IN IONIC LIQUIDS VIA ELECTROCHEMICAL GENERATION OF CARBENE

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