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GaAsN/GaAsSb superlattices as 1 eV layers for efficient multi-junction solar cells

机译:GaAsN / GaAsSb超晶格为1 eV层,用于高效多结太阳能电池

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We demonstrate type-II GaAsSb/GaAsN superlattices as a suitable candidate to form a lattice-matched 1.01.15 eV subcell that could significantly improve the performance of multi-junction solar cells. The spatial separation of N and Sb allows better lattice-matching control, composition homogeneity, crystal quality and interface abruptness. Moreover, the type-II band alignment provides effective bandgap and radiative lifetime tunability through the period thickness. For the impact of period thickness on transport, quantum-kinetic simulations support the experimental finding of efficient carrier extraction at thicknesses up to 6 nm. All this leads to single-junction solar cells with improved efficiency under monochromatic illumination over the equivalent bulk devices.
机译:我们证明了II型GaAsSb / GaAsN超晶格作为形成晶格匹配的1.01.15 eV子电池的合适候选物,可以显着提高多结太阳能电池的性能。 N和Sb的空间分隔可实现更好的晶格匹配控制,成分均匀性,晶体质量和界面突变性。此外,II型能带对准可在整个周期厚度内提供有效的能带隙和辐射寿命可调性。对于周期厚度对传输的影响,量子动力学模拟支持实验发现在厚度最大为6 nm时有效的载流子提取。所有这些导致单结太阳能电池在单色照明下具有比同等体积的装置更高的效率。

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