首页> 外文会议>World Tribology Congress III vol.1; 20050912-16; Washington,DC(US) >NANO/MICRO-RHEOLOGY OF PERFLUOROPOLYETHER LUBRICANTS
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NANO/MICRO-RHEOLOGY OF PERFLUOROPOLYETHER LUBRICANTS

机译:全氟橡胶润滑剂的纳米/微流变学

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摘要

The bulk rheological properties, such as shear viscosity and storage & loss moduli of perfluoropolyether (PFPE) with different molecular weights and endgroup functionalities were examined via a rotational rheometer. Equilibrium and non-equilibrium molecular dynamics simulations were performed to provide a molecular visualization tool to clearly understand the intrinsic nanostructure as well as to predict the bulk shear viscosity, which reveals a strong dependence on temperature and PFPE molecular architecture.
机译:通过旋转流变仪检查了具有不同分子量和端基官能团的全流变性质,例如剪切粘度和全氟聚醚(PFPE)的储能和损耗模量。进行了平衡和非平衡分子动力学模拟,以提供一种分子可视化工具,以清楚地了解内在的纳米结构以及预测整体剪切粘度,从而揭示了对温度和PFPE分子结构的强烈依赖性。

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