声明
摘要
Acknowledgements
ABSTRACT
Table of Contents
Chapter 1.Literature review
1.1.Introduction
1.2.Synthesis of ferrocene-based polymers
1.2.1.Synthesis of main-chain ferrocene-based polymers
1.2.2.Synthesis of side-chain ferrocene-based polymers
1.3.Properties and appfications of ferrocene-based polymers
1.3.1.Liquid-crystalline properties and applications
1.3.2.The electrochemical properties and applications
1.3.3.Applications based on the collective properties
1.3.4.Biological appfications
1.4.Research Objectives
Chapter 2.Synthesis and properties of main-chain ferrocene-based polymers containing diethylene glycol or bis (4-hydroxyoctoxy phenyi) sulfone
2.1.Introduction
2.2.Experimental
2.2.1.Materials
2.2.2.Schlenk fine system
2.2.3.Synthesis of 1,1’-ferrocenedicarbonyl chloride
2.2.4.Synthesis of HOS
2.2.5.Synthesis of PDEFD
2.2.6.Synthesis of PHOSFD
2.2.7.Characterization
2.3.Results and discussion
2.3.1.Synthesis and characterization of HOS,PDEFD and PHOSFD
2.3.2.Electrochemical properties of PDEFD and PHOSFD
2.3.3.Thermal and liquid crystalfine properties of PDEFD and PHOSFD
2.4.Conclusion
Chapter3.Synthesis and properties of novel main-chain ferrocene-based polymers containing N-methyldiethanolamine,phenyldiethanolamine or bisphenol-P
3.1.Introduction
3.2.Experimental
3.2.1.Materials
3.2.2.Synthesis of PPFD and PHDFD
3.2.3.Synthesis of PMFD
3.2.4.Characterization
3.3.Results and discussion
3.3.1.Synthesis and characterization of the main-chain ferrocene-based polyesters
3.3.2.Electrochemical properties of the main-chain ferrocene-based polyesters
3.3.3.Thermal and liquid-crystalline properties of the main-chain ferrocene-based polyesters
3.4.Conclusion
Chapter 4.Synthesis and properties of main-chain ferrocene-based polyesters with azobenzene in the side-chain
4.1.Introduction
4.2.Experimental
4.2.1.Materials
4.2.2.Synthesis of PPFD-NT,PPFD-CA and PPFD-CN
4.2.3.Characterization
4.3.Results and Discussion
4.3.1.Synthesis and characterization of the azobenzene-containing main-chain ferrocene-based polyesters
4.3.2.Photoisomerization of the synthesized MFPAS
4.3.3.Azo-protonation of the azobenzene-containing main-chain ferrocene-based polyesters
4.3.4.Thermal and liquid crystalline properties of the azobenzene-containing main-chain ferrocene-based polyesters
4.4.Conclusion
Chapter 5.Synthesis,characterization and properties of some main-chain ferrocene-based polymers containing aliphatic units
5.1.Introduction
5.2.Experimental
5.2.1.Materials
5.2.2.Synthesis of PSPUFD and PDAFD
5.2.3.Synthesis of PDMFD and PHPFD
5.2.4.Characterization
5.3.Results and discussion
5.3.1.Synthesis and characterization of the main-chain ferrocene-based polymers containing aliphatic units
5.3.2.Electrochemical properties of the aliphatic main-chain ferrocene based polymers
5.3.3.Thermal and liquid crystalline properties of the aliphatic main-chain ferrocene-based polymers
5.4.Conclusion
Chapter 6.Synthesis,characterization and properties of some main-chain ferrocene-based polymers containing aromatic units
6.1.Introduction
6.2.Experimental
6.2.1.Materials
6.2.2.Synthesis of PCPFD and PCRFD
6.2.3.Synthesis of PQDFD and PSOFD
6.2.4.Characterization
6.3.Resuits and discussion
6.3.1.Synthesis and characterization of the main-chain ferrocene-based polymers containing aromatic units
6.3.2.Electrochemical properties of the aromatic main-chain ferrocene-based polymers
6.3.3.Thermal and liquid crystalline properties of the aromatic main-chain ferrocene-based polymers
6.4.Conclusion
Chapter 7.Conclusion
References
Curriculum Vitae