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Toward the Synthesis of Organic Moieties for use in Luminescent Lanthanide Materials: From Benzodithiophene Based Linkers to a Series of 2,3-Pyridinedicarboxylate Coordination Polymers.

机译：迈向用于发光镧系材料的有机部分的合成：从基于苯并二噻吩的连接剂到一系列2,3-吡啶二羧酸酯配位聚合物。

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The main focus of this thesis is to present the structural and photophysical characteristics of the coordination polymers [Ln(C7H3NO 4)(C7H4NO4)(H2O)]n (Ln is Pr, Nd, Sm, Eu, and Tb), as well as attempting to synthesize the novel organic linker 4,4'(4,8-Dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-diyl)dibenzoic acid (BDTDC).;Various lanthanide salts were coordinated with 2,3-pyridinecarboxylate (2,3- pydc) via hydrothermal synthesis. These coordination polymers exhibited luminescent properties with quantum yields of 2.6 +/- 0.28% (Eu), 4.6 +/- 0.18% (Tb), and 0.60 +/- 0.02% (Sm) found as well as lifetime values, 0.53 +/- 0.01 ms (Eu), 1.21 +/- 0.10 ms (Tb), and 0.19 +/-0.10 ms (Sm). The singlet and triplet state of the 2,3-pydc linker were determined to be 27,470 +/- 350cm-1 and 22,570 +/- 50cm -1 respectively.;Progress was made toward the synthesis of a novel metal-organic framework linker BDTDC. Synthesis of the intermediate benzo[1,2-b:4,5-b']dithiophene as well as the determination of the crystal structure, were performed successfully and are reported herein.

机译：本论文的主要重点是介绍配位聚合物[Ln（C7H3NO 4）（C7H4NO4）（H2O）] n（Ln为Pr，Nd，Sm，Eu和Tb）的结构和光物理特性，以及尝试合成新型有机连接基4,4'（4,8-二氢苯并[1,2-b：4,5-b']二噻吩-4,8-二基）二苯甲酸（BDTDC）。通过水热合成与2,3-吡啶羧酸盐（2,3-pydc）配位这些配位聚合物表现出发光特性，量子产率为2.6 +/- 0.28％（Eu），4.6 +/- 0.18％（Tb）和0.60 +/- 0.02％（Sm）以及寿命值0.53 + / -0.01毫秒（Eu），1.21 +/- 0.10毫秒（Tb）和0.19 +/- 0.10毫秒（Sm）。确定了2,3-pydc接头的单重态和三重态分别为27,470 +/- 350cm-1和22,570 +/- 50cm -1 .;向合成新型金属有机骨架接头BDTDC的方向发展。中间体苯并[1,2-b：4,5-b']二噻吩的合成以及晶体结构的测定已成功进行，并在本文中进行了报道。

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Ramirez, Amanda Lyn Staggers.;
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Florida Atlantic University.;

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授予单位 Florida Atlantic University.;
学科 Chemistry.;Organic chemistry.
学位 M.S.
年度 2013
页码 74 p.
总页数 74
原文格式 PDF
正文语种 eng
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1. Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate [J] . Zhuo Wang, Feng-Ying Bai, Yong-Heng Xing, Inorganica Chimica Acta . 2010,第4期

机译：基于癸二酸酯和2,5-吡啶二甲酸的镧系元素第一批配合物的合成和发光性质
2. Structure and luminescence of a 2-dimensional 2,3-pyridinedicarboxylate coordination polymer constructed from lanthanide(III) dimers [J] . Ramirez A.L., Knope K.E., Kelley T.T., Inorganica Chimica Acta . 2012,第Null期

机译：由镧系元素（III）二聚体构成的二维2,3-吡啶二羧酸酯配位聚合物的结构和发光
3. Discrete Polyoxovanadate Cluster into an Organic Free Metal-Oxide-Based Material: Syntheses, Crystal Structures, and Magnetic Properties of a New Series of Lanthanide Linked-POV Compounds [{Ln(H2O)6}2As8V14O42(SO3)]·8H2O (Ln = La3+, Sm3+, and Ce3+) [J] . Arumuganathan T, Das SK Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第2期

机译：离散的聚氧钒酸盐簇簇为基于有机金属氧化物的材料：一系列新的镧系键合POV化合物[{Ln（H2O）6} 2As8V14O42（SO3）]·8H2O的合成，晶体结构和磁性La3 +，Sm3 +和Ce3 +）
4. Chapter 21 Sol–Gel Organic–Inorganic Hybrid Materials Containing Lanthanide Complexes with Polydentate Acyclic and Cyclic Ligands: Synthesis and Spectral-Luminescent Properties [C] . S. S. Smola, O. V. Snurnikova, E. N. Fadeyev, International Summer School Nanotechnology : From Fundamental Research to Innovations . 2013

机译：第21章溶胶 - 凝胶有机 - 无机杂化材料，含有镧系有镧系元素的镧系元素和环状配体：合成和光谱发光性能
5. Inorganic-organic hybrid materials: Main group halometallate materials and coordination polymers. [D] . Goforth, Andrea Mitchell. 2005

机译：无机-有机杂化材料：主族卤化金属材料和配位聚合物。
6. Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry [O] . Pierre Farger, Cédric Leuvrey, Mathieu Gallart, 2018

机译：基于咪唑鎓盐和镧系元素的磁性和发光配位网络用于灵敏的比例温度法
7. Thin films of highly luminescent lanthanide complexes covalently linked to an organic-inorganic hybrid material via 2-substituted imidazo4,5-f-1,10-phenanthroline groups [O] . Lenaerts Philip, Storms A, Mullens J, 2005

机译：高发光度镧系元素络合物薄膜通过2-取代的咪唑并4,5-f -1,10-菲咯啉基团共价连接至有机-无机杂化材料

Toward the Synthesis of Organic Moieties for use in Luminescent Lanthanide Materials: From Benzodithiophene Based Linkers to a Series of 2,3-Pyridinedicarboxylate Coordination Polymers.

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