Synthesis and structure of trans-dialkene complexes of platinum(II).

机译：铂（II）的反式二烯烃配合物的合成和结构。

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This thesis examines the synthesis and characterization of trans -dialkene platinum complexes with cycloalkenes. The first step was to synthesize trans-[PtCl2(eta2-cot) 2] (cot = cyclooctene) which have been previously reported in the literature to be sure we have mastered the techniques to prepare this unusual type of complex. Once this compound was synthesized we used a similar strategy to react 2 and 4 molar equivalents the Z-cyclohexene, Z-cycloheptene, E-cyclodecene, and E/Z-cyclododecene with Zeise's dimer. We also reacted 2 and 4 molar equivalents of rigid ring-bridged cylcoalkenes such as bicylo[2.2.1]hept-2-ene, and bicylo[3.2.1]oct-2-ene with Zeise's dimer. As a result of this research we successfully synthesized the trans-dialkene compound of E-cyclodecene and its Zeise's dimer analogue. We also synthesized Zeise's dimer analogues of E/Z-cyclododecene and bicyclo[2.2.1]hept-2-ene which have not been previously reported in the literature.

机译：本文研究了反式-二烯烃铂与环烯烃的配合物的合成与表征。第一步是合成反式-[PtCl2（eta2-cot）2]（cot =环辛烯），以前在文献中已有报道，以确保我们掌握了制备这种不寻常类型复合物的技术。合成该化合物后，我们将使用相似的策略使2和4摩尔当量的Z-环己烯，Z-环庚烯，E-环癸烯和E / Z-环十二碳烯与Zeise's二聚体反应。我们还使2和4摩尔当量的刚性环桥联环烯烃与双环[2.2.1]庚-2-烯和双环[3.2.1]辛-2-烯与Zeise's二聚体反应。这项研究的结果是，我们成功地合成了E-环癸烯的反式二烯烃化合物及其Zeise的二聚体类似物。我们还合成了E / Z-环十二碳烯和双环[2.2.1]庚-2-烯的Zeise's二聚体类似物，以前在文献中没有报道过。

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作者
Hay, Jeremy Jon.;
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Indiana University of Pennsylvania.;

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授予单位 Indiana University of Pennsylvania.;
学科 Chemistry General.;Chemistry Inorganic.
学位 M.S.
年度 2012
页码 87 p.
总页数 87
原文格式 PDF
正文语种 eng
中图分类宗教;
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Synthesis and structure of trans-dialkene complexes of platinum(II).

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