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Printing carbon nanotube based supercapacitors for packaging.

机译:印刷用于包装的基于碳纳米管的超级电容器。

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摘要

Living in a world full of portable electronics, there is great need for energy storage devices. Currently, limitations for storage involve power inefficiencies as well as bulkiness. This is why printable charge storage devices that display good electrochemical performance are needed. It is for this reason that research into the production and packaging of carbon nanotube based super capacitors was carried out.;A supercapacitor can be built by using high surface area multi-walled carbon nanotubes suspended in an ionic liquid. The two active electrodes are made from a combination of the multi-walled carbon nanotubes and an ionic liquid, ground into a gel, and then formulated into a printable functional ink. The super capacitor is then built upon a conducting carbon foam substrate where the two electrodes are printed and sandwiched on top of a membrane that allows ion-ion transfer without allowing any physical exchange of nanotube particles.;The purpose of this research was to find a printing method or technique that produced functional carbon nanotube based electrodes for supercapacitor assembly. This process involved changing printing variables such as the mesh count for the screen, the type of stencil used, and the thickness of the emulsion applied.;Other variables altered for this study focused on the ink formulation portion of the testing. These variables included creating a medium that dispersed the carbon nanotubes, chemical carrier agents for the carbon nanotubes and ionic liquid, ionic liquid selection, concentration of the chemical to the bucky gel relationship, temperature used for curing the ink, and the influence of adhesive agents present in the ink.;The printed electrodes were assembled with the separator membrane into supercapacitors that were then measured in the electrochemical cell. The charge/discharge curves were used to calculate the current density and specific capacitance of each combination of supercapacitors.;Supercapacitors made of printed electrodes that were 40% bucky gel and 60% 1-methyl-2-pyrrolidinone (with the bucky gel as 9.82% multi-walled carbon nanotubes, 88.42% ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate, and 1.76% TeflonRTM binder) were found to perform the best out of all other combinations of electrodes printed on carbon foam substrate. All printed electrodes had measurable results except for those printed on aluminum substrate.
机译:生活在充满便携式电子设备的世界中,非常需要储能设备。当前,存储的限制涉及功率效率低下以及体积大。这就是为什么需要显示出良好电化学性能的可印刷电荷存储装置的原因。因此,对基于碳纳米管的超级电容器的生产和包装进行了研究。通过使用悬浮在离子液体中的高表面积多壁碳纳米管可以构建超级电容器。两个活性电极由多壁碳纳米管和离子液体的组合制成,研磨成凝胶,然后配制成可印刷的功能性墨水。然后,将超级电容器构建在导电碳泡沫基材上,在该基材上印刷两个电极并将其夹在膜的顶部,该膜允许离子转移而不允许任何纳米管颗粒的物理交换。;本研究的目的是找到一种生产用于超级电容器组件的基于功能性碳纳米管的电极的印刷方法或技术。此过程涉及更改印刷变量,例如丝网的网眼数,使用的模板类型和所施加的乳剂厚度。;本研究中更改的其他变量着重于测试的油墨配方部分。这些变量包括创建一种分散碳纳米管的介质,用于碳纳米管和离子液体的化学载体,离子液体的选择,化学物质与Bucky凝胶的浓度关系,用于固化墨水的温度以及粘合剂的影响印刷电极与隔离膜组装成超级电容器,然后在电化学电池中进行测量。充电/放电曲线用于计算每种超级电容器组合的电流密度和比电容;由印刷电极制成的超级电容器,印刷电极为40%的Bucky凝胶和60%的1-甲基-2-吡咯烷酮(bucky凝胶为9.82已发现,在50%的多壁碳纳米管,88.42%的离子液体1-乙基-3-甲基咪唑鎓乙基硫酸盐和1.76%的TeflonRTM粘合剂中,在印刷在碳泡沫基材上的所有其他电极组合中表现最佳。除了印刷在铝基板上的电极以外,所有印刷电极均具有可测量的结果。

著录项

  • 作者

    Hartman, Alexandra.;

  • 作者单位

    Clemson University.;

  • 授予单位 Clemson University.;
  • 学科 Engineering Packaging.;Engineering Materials Science.
  • 学位 M.S.
  • 年度 2011
  • 页码 128 p.
  • 总页数 128
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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