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Synthesis and characterization of tetraalkylated and functionalized polyalkylated ferrocenes and their applications for the selective redox-recyclable extraction and detection of aqueous anions.

机译：四烷基化和功能化的聚烷基化二茂铁的合成，表征及其在选择性氧化还原可循环萃取和检测含水阴离子中的应用。

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Several new tetraalkylated ferrocenes and functionalized polyalkylated ferrocenes have recently been synthesized and used for the selective ion exchange and detection of aqueous anions. The synthesis of new, functionalized polyalkylated ferrocenes is key to the development of novel, robust ion exchange compounds that can be used in materials synthesis or surface modification. The resulting materials have applications in both the remediation and detection of pollutant anions in aqueous media. The goal of this work is the synthesis and characterization of several novel polyalkylated ferrocenes and the study of their applications toward the remediation and detection of aqueous media containing pollutant anions. Several new functionalized polyalkylated ferrocenes have been synthesized and used for materials synthesis or surface modification toward this end. In addition, a novel method of electrochemical anion detection is discussed using some of the electroactive polyalkylated ferrocenyl materials synthesized. Due to the importance of selectivity for both remediation and detection, the ion-exchange selectivity of these novel polyalkylated ferrocenes for both applications was determined as further characterization of the new ion-exchange materials.

机译：最近已经合成了几种新的四烷基化二茂铁和官能化的聚烷基化二茂铁，并用于选择性离子交换和含水阴离子的检测。新型，功能化的聚烷基化二茂铁的合成是开发可用于材料合成或表面改性的新型耐用离子交换化合物的关键。所得材料可用于水介质中污染物阴离子的修复和检测。这项工作的目的是合成和表征几种新型的多烷基二茂铁，并研究其在修复和检测含污染物阴离子的水性介质中的应用。为此已经合成了几种新的官能化的聚烷基化二茂铁，并用于材料合成或表面改性。另外，讨论了使用一些合成的电活性聚烷基化二茂铁基材料的新型电化学阴离子检测方法。由于选择性对于修复和检测都很重要，因此确定了这些新型聚烷基化二茂铁在两种应用中的离子交换选择性，作为对新型离子交换材料的进一步表征。

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作者
Clapsaddle, Brady John.;
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作者单位

Colorado State University.;

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授予单位 Colorado State University.;
学科 Chemistry Inorganic.
学位 Ph.D.
年度 2002
页码 286 p.
总页数 286
原文格式 PDF
正文语种 eng
中图分类无机化学;
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Synthesis and characterization of tetraalkylated and functionalized polyalkylated ferrocenes and their applications for the selective redox-recyclable extraction and detection of aqueous anions.

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