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The chemistry of phosphites, phosphonates and spiroxyphosphoranes: Novel applications to asymmetric synthesis.

机译：亚磷酸酯，膦酸酯和螺氧基磷烷的化学反应：不对称合成的新应用。

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The work detailed within this dissertation is aimed at the development of new methodologies for the asymmetric syntheses of ;Chapter I describes the results obtained in the study of the oxidation of ;Chapter II discusses original synthetic methods that were developed to effect the asymmetric synthesis of ;Chapter III summarizes the new advances made in the chemistry of spiroxyphosphoranes and the utility of their conjugate bases in olefination reactions. Low reactivity of the spiroxyphosphorane anions towards ketones was demonstrated. The structure of the carbon-lithium and carbon-silicon bonds in some spiroxyphosphorane derivatives was elucidated on the basis of low temperature NMR studies.

机译：本论文详细研究的目的是开发新的不对称合成方法；第一章描述了氧化研究的结果；第二章讨论了影响不对称合成的原始合成方法。第三章总结了螺氧基膦的化学反应及其在共轭碱中的应用。展示了螺氧基磷烷阴离子对酮的低反应性。在低温NMR研究的基础上，阐明了某些螺氧基磷烷衍生物中的碳锂键和碳硅键的结构。

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作者
Lefebvre, Isabelle M.;
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作者单位

The University of North Carolina at Chapel Hill.;

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授予单位 The University of North Carolina at Chapel Hill.;
学科 Chemistry Organic.
学位 Ph.D.
年度 1998
页码 169 p.
总页数 169
原文格式 PDF
正文语种 eng
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1. First P,P-bidentate phosphine-phosphite-type ligand with a P-stereocenter in the phosphite moiety: synthesis and application in the Pd-catalyzed asymmetric allylic alkylation [J] . K. N. Gavrilov, S. V. Zheglov, A. A. Shiryaev Russian Chemical Bulletin . 2013,第4期

机译：首个在亚磷酸酯部分具有P-立体中心的P，P-二齿膦-亚磷酸酯型配体：在Pd催化的不对称烯丙基烷基化反应中的合成及应用
2. Tuning of the structures of chiral phosphane-phosphites: Application to the highly enantioselective synthesis of alpha-acyloxy phosphonates by catalytic hydrogenation [J] . Rubio M, Vargas S, Suarez A, Chemistry: A European journal . 2007,第6期

机译：手性膦-亚磷酸酯的结构调整：通过催化氢化在高对映选择性合成α-酰氧基膦酸酯中的应用
3. Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B_1) [J] . Zhongmin Xu, Charles W. Johannes, Ahmad F. Houri Journal of the American Chemical Society . 1997,第43期

机译：Zr催化的碳镁化反应和Mo催化的大环闭环置换在不对称合成中的应用。 Sch 38516（Fluvirucin B_1）的对映选择性全合成
4. Axial Chirality Chemistry: Asymmetric Catalysis and Applications [C] . Bin Tan, Yong-Bin Wang, Jian Zhang 日本化学会春季年会講演予稿集 . 2018

机译：轴向手性化学：不对称催化和应用
5. The chemistry of some novel nicotineseleno and camphorseleno compounds: Applications to asymmetric synthesis. [D] . Dyck, Brian Peter. 1997

机译：一些新的烟碱硒代和樟脑硒代化合物的化学性质：在不对称合成中的应用。
6. Facile and efficient Lewis acid catalyzed synthesis of an asymmetric tetrazine useful for bio-orthogonal click chemistry applications [O] . Daniel L. Alge, Dillon F. Donohue, Kristi S. Anseth -1

机译：简便有效的路易斯酸催化的不对称四嗪的合成可用于生物正交点击化学应用
7. XLI.—Studies in asymmetric synthesis. IV. The application of Grignard's reaction for asymmetric syntheses [O] . Alexander McKenzie 1906

机译：XLI.-非对称合成研究。 IV。格氏反应对不对称合成的应用
8. Quantum Chemical Study of the Phosphite-Phosphonate Tautomerization: Applications to bis(2-Ethylhexyl) Phosphonate (BIS) and Other Simulants for Chemical Warfare Agents [R] . White, W. E. 2002

机译：亚磷酸酯 - 膦酸酯互变异构化的量子化学研究：双（2-乙基己基）膦酸酯（BIs）和化学战剂的其他模拟物的应用

The chemistry of phosphites, phosphonates and spiroxyphosphoranes: Novel applications to asymmetric synthesis.

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