A new 1D complex [ Ag(im2-py ) ( CN) ] n ( im2-py = 2-( 2'-pyridyl) -4,4,5,5-tetramethylimidazoline-l-oxyl) has been synthesized by reaction of dicyanoethyl siller salt and nitronyl nitroxide and structurally determined by X-ray diffraction, elemental analysis,IR and Uv-visble. Crystal structural analysis reveals that the complex is Orthorhombic system,space group P21 21 21 with the cell pararoeters:a= 9.6074(6)(A),b = 9.8668(8)(A),c=14.8589(14)(A),V=1408.5(2)(A)3,Z = 4,R1 = 0.0594, wR2 = 0.121. The Ag(Ⅰ)ions are four-coordinated as slightly distorted tetrahedronc. Each cyanide dianion binds two Ag(Ⅰ)ions in a mono-dentate leading to a 1-D chain structure. The 1 D chain forms a 2 D network through intermolecular C-H-O and C-H--N hydrogen bonds.%用二氰化银盐(Ag(CN)2-)和氮氧自由基反应合成了一种新的一维配合物[Ag(im2-py) (CN)]n(im2-py=2-(2′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl).利用X-射线单晶衍射、元素分析、红外和紫外光谱进行了表征.晶体结构分析表明,配合物品体属正交晶系,空间群P212121,晶胞参数:a=9.6074 (6)(A),b=9.8668(8)(A),c=14.8589(14)](A),V=1408.5(2)(A)3,Z=4,R1=0.0594,wR2=0.121.配合物晶体结构中,每个Ag(Ⅰ)采用四配位的变形四面体构型,每个氰根阴离子通过单齿配位模式连接两个Ag(Ⅰ)离子形成一维链状结构,一维链状结构通过分子间的C-H…O和C-H…N氢键作用扩展为二维网状结构.
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