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《中国化学快报：英文版》
>Oxidative Methylation of Toluene with Methane over Basic Zeolite Catalysts Promoted with Alkali Metal Bromides and Alkali Metal Oxides
Oxidative Methylation of Toluene with Methane over Basic Zeolite Catalysts Promoted with Alkali Metal Bromides and Alkali Metal Oxides
The catalytic effects for the oxidative methylation of toluene with methane over the basic zeolite catalysts prepared by promoting KY, KX, KM, KZSM-5 or Kβ with alkali-metal bromides and alkali-metal oxides have been investigated comparatively. The alkali-metal bromides promoted substrates are more effective than the alkali-metal oxides promoted systems. Moreover, the NaBr promoted systems are more active than KBr promoted systems. The most effective catalytic system （8wt%NaBr）/KZSM-5 gave a toluene conversion as high as 76.3% and a total C8 selectivity of 76.4% （styrene/ethylbenzene=9.76） resulting in a total C8 yield of 58.3%.
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机译：High-resolution structural studies of ultra-thin magnetic, transition metal overlayers and two-dimensional transition metal oxides using synchrotron radiation
