首页> 中文期刊> 《中国有色金属学报:英文版》 >Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3(Ln = Sc,La,Nd,Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3(Ln = Sc,La,Nd,Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

         

摘要

Mutual separation characteristics for binary oxide mixtures Y2O3-Sc2O3, Y2O3-La2O3, Y2O3-Nd2O3 and Y2O3-Sm2O3 using a stepwise selective chlorination-chemical vapor transport(SC-CVT) reaction mediated by vapor complexes KLnCl4 were investigated. The total transported yields of the chlorides produced from the oxide mixtures are in the order of NdCl3>SmCl3>LaCl3>YCl3>ScCl3, the main deposition temperature of the chlorides is in the order of ScCl3

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