Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3 (Ln = Sc, La, Nd, Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

SUN Yan-hui; CHEN Zhen-fei; WANG Zhi-chang

首页> 外文期刊>Transactions of Nonferrous Metals Society of China >Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3 (Ln = Sc, La, Nd, Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

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Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3 (Ln = Sc, La, Nd, Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

机译：蒸气络合物KLnCl_4介导的逐步选择性氯化-化学气相转移反应实现二元氧化物Y_2O_3-Ln_2O_3（Ln = Sc，La，Nd，Sm）的相互分离特性

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Mutual separation characteristics for binary oxide mixtures Y_2O_3-Sm_2O_3, Y_2O_3-La_2O_3, Y_2O_3-Nd_2O_3 and Y_2O_3-Sm_2O_3 using a stepwise selective chlorination-chemical vapor transport(SC-CVT) reaction mediated by vapor complexes KLnCl_4 were investigated. The total transported yields of the chlorides produced from the oxide mixtures are in the order of NdCl_3 >SmCl_3 >LaCl_3 >YCl_3>ScCl_3, the main deposition temperature of the chlorides is in the order of ScCl_3

机译：利用蒸汽络合物KLnCl_4介导的逐步选择性氯化-化学气相输送（SC-CVT）反应，研究了二元氧化物混合物Y_2O_3-Sm_2O_3，Y_2O_3-La_2O_3，Y_2O_3-Nd_2O_3和Y_2O_3-Sm_2O_3的相互分离特性。由氧化物混合物产生的氯化物的总运输产率为NdCl_3> SmCl_3> LaCl_3> YCl_3> ScCl_3的顺序，氯化物的主要沉积温度为ScCl_3

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《Transactions of Nonferrous Metals Society of China》 |2004年第2期|p.412-416|共5页
作者
SUN Yan-hui; CHEN Zhen-fei; WANG Zhi-chang;
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作者单位

Department of Chemistry, South China Normal University, Guangzhou 510631, China;

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原文格式 PDF
正文语种 eng
中图分类有色金属冶炼;
关键词
rare earth oxides; separation; chemical vapor transport reaction; KLnCl_4;

机译：稀土氧化物分离化学气相传输反应KLnCl_4;

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1. Comparative study for mutual separation characteristics of binary mixed oxides Y_2O_3-Ln_2O_3 (Ln = Dy, Ho and Er) and Ho_2O_3-Er_2O_3 using stepwise chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4 [J] . Yan-Hui Sun, Zhen-Fei Chen, Peng He Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2005,第1a2期

机译：蒸汽络合物KLnCl_4介导的逐步氯化-化学气相转移反应对二元混合氧化物Y_2O_3-Ln_2O_3（Ln = Dy，Ho和Er）和Ho_2O_3-Er_2O_3相互分离特性的比较研究
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3. Mutual separation characteristics for binary mixed oxides Ho_2O_3-Ln_2O_3 (Ln = Sc, Y, La, Nd, Sm) using stepwise chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4 [J] . Y.-H. Sun, Z.-F. Chen, Z.-C. Wang Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2004,第1a2期

机译：二元混合氧化物Ho_2O_3-Ln_2O_3（Ln = Sc，Y，La，Nd，Sm）的相互分离特性，采用由蒸汽络合物KLnCl_4介导的逐步氯化-化学气相转移反应
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Mutual separation characteristics for binary oxides Y_2O_3-Ln_2O_3 (Ln = Sc, La, Nd, Sm) using stepwise selective chlorination-chemical vapor transport reaction mediated by vapor complexes KLnCl_4

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