非晶态介孔FeAlP催化剂用于合成1,5-苯二氮类化合物(英文)

A.V.VIJAYASANKAR; S.DEEPA; B.R.VENUGOPAL; N.NAGARAJU

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非晶态介孔FeAlP催化剂用于合成1,5-苯二氮类化合物(英文)

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摘要

A simple and versatile method for the synthesis of 1,5-benzodiazepines from o-phenylenediamine and ketones in the presence of solvents and under solvent-free conditions that used an amorphous mesoporous iron aluminophosphate as catalyst was developed.High yields with excellent selectivity were obtained with a wide variety of ketones under mild reaction conditions.The catalyst had the advantages of ease of preparation,ease of handling,simple recovery,reusability,non toxicity,and being inexpensive.

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来源
《催化学报》 |2010年第11期|1321-1327|共7页
作者
A.V.VIJAYASANKAR; S.DEEPA; B.R.VENUGOPAL; N.NAGARAJU;
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作者单位

Department of Chemistry;

Catalysis Research Laboratory;

St.Joseph's College Research Centre;

Department of Organic Chemistry;

Indian Institute of Science;

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原文格式 PDF
正文语种 chi
中图分类化学动力学、催化作用;
关键词
benzodiazepine; amorphous metal aluminophosphate; mesoporous iron aluminophosphate; o-phenylenediamine; ketone; solvent free synthesis;

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非晶态介孔FeAlP催化剂用于合成1,5-苯二氮类化合物(英文)

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