Two novel complexes,[CoⅡCoⅢ4(salhn)4(N3)6(CH3OH)2(H2O)2]·4CH3OH·2H2O (1) and [Cu2(salhn)(N3)2]n (2) (H2salhn=N,N′-bis(salicylidene)hydrazine),were synthesized and structurally characterized by X-ray singlecrystal diffraction.Complex 1 is a zigzag-like penta-nuclear [CoⅡCoⅢ4] cobalt cluster,while complex 2 consists of a 1D chain containing subunit [Cu2(salhn)(N3)2].Both complexes possess bridged azide with the end-on (EO,μ-1,1) coordination fashion.The magnetic measurements indicate that 1 and 2 both show antiferromagnetic behaviors.CCDC:869426,1;869427,2.%合成了2个化合物[CoⅡCoⅢ4(salhn)4(N3)6(CH3OH)2(H2O)2]·4CH3OH ·2H2O (1)和[Cu2 (salhn) (N3)2]n(2) (H2salhn =N,N′-bis (salicylidene)hydrazine),并用X射线单晶衍射进行结构表征.化合物1是一个五核的[CoⅡCoⅢ4]钴簇,而化合物2是一个具有结构单元为[Cu2(salhn)(N3)2]的一维链结构.2个化合物中叠氮均具有end-on(EO,μ-1,1)的配位模式.化合物1和2的磁学性质测试表明它们都具有反铁磁行为.
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