本文合成了2个大环硒杂二茂铁环蕃,1,9-二硒杂-5-硫杂[9]二茂铁环蕃(1)和1,9,21,29-四硒杂-5,25-二硫杂[9.9]二茂铁环蕃(2),并应用核磁、质谱、单晶X-射线衍射进行了表征.循环伏安法测得二茂铁的氧化还原半波电位分别为-30 (81) mV (1)和42(67) mV (2).%Two macrocyclic ferrocenophanes,1,9-diselena-5-sulfur-[9]ferrocenophane (1) and 1,9,21,29-tetraselena -5,25-disulfur-[9.9]ferrocenophane (2),have been prepared.The new compounds have been characterized by 1H NMR spectroscopy,X-ray crystallography and electrochemistry.The CV of 1 and 2 showed one clearly reversible oxidation process with E1/2 value of-30(81) mV and 42(67) mV respectively.CCDC:849326,1; 849327,2.
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