In the tide compound,[Pb_2(C_8H_4O_4)_2(C_(19)H_(12)N_4O)_2]_n·3.5nH_2O(1),has been synthesized by the hydrothermal assembly of 1,4-benzenedicarboxylate and 4-(1H-1,3,7,8-tetraazacyclopenta[l]-phenanthren-2-yl)phenol(TCPP)with lead acetate.Elemental analysis,X-ray crystal structure analysis,IR spectrum,thermogravimetric analysis and luminescence property were carried out for the structural determination and characterization of the title compound.Compound 1 crystallizes in triclinic,space group P1 with a=1.013 54(10)nm,b=1.104 84(11)nm,C=1.21005(12)nm,a=76.8120(10)°,β=74.8140(10)°,γ=86.0300(10)°,V=1.2731(2)nm3,Pb_2C_(54)H_(39)N_8O_(13.5):1430.31,Z=1,D_c=1.866·cm~(-3),μ=6.680mm~(-1),F(000)=691,R=0.0273 and wR=0.0687 for 4042 observede reflections(I>2σ(I)).The compound l exhibits two-dimensional network structures.which are further stacked through π-π interactions and hydrogen bonds to form three-dimensional supramolecular polymer.Solid-state luminescent spectrum of the compound 1 indicates intense fluorescent emission.
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