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《结构化学》
>A Pair of 3D Homochiral Coordination Polymers with Open Channels Constructed by Lactic Acid Derivative Ligands and In-situ Formed Anions
A Pair of 3D Homochiral Coordination Polymers with Open Channels Constructed by Lactic Acid Derivative Ligands and In-situ Formed Anions
With the help of in-situ formed CH3COO anion,a pair of 3D homochiral coordination polymers with open channels were constructed by the assembly of lactic acid derivative ligands,1.4-DIB ligands and Cd(Ⅱ) ions,namely [Cd3((R)-CIA)2(CH3CO2)2(1.4-DIB)2(H2O)2]·x(Guest) (1-D)and [Cd3((S)-CIA)2(CH3CO2)2(1.4-DIB)2(H2O)2]·x(Guest) (1-L).They contain ID interesting ladder-like Cd-(R)-CIA3-chains and exhibit SHG-active behavior and photoluminescent property.
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