采用振荡式球磨机作为机械能发生装置，分别研究了5-氨基间苯二甲酸(H2AIP)和乙酸铜或乙酸钴的机械化学反应。结果表明，当在振荡式球磨机(20 Hz)中球磨30 min促使生成2维聚合物：[Cu(HAIP)2]•H2O和[Co(HAIP)2(H2O)2]•2H2O。%In a shaking ball mill , the mechanochemical reactions between 5-aminoisophthalic acid and Cu(OAc)2•H2O or Co(OAc)2•4H2O have been studied. The results show that ball milling of the starting materials in the shaking (at 20 Hz) ball mill, two bidimensional coordination compounds, [Cu(HAIP)2]•H2O and [Co(HAIP)2(H2O)2]•2H2O are obtained successfully under neat granding.
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