The organometallic complex: [PhNSi(Me)(NMe2)NHPh]ZrLiCl4(Et2O)2 was synthesized by the reactions of ZrCl4 with Li [N (Ph)SiMe (NMe2)NHPh],and the complex was characterized by crystal X-ray diffraction,1H NMR,13C NMR.The crystal is monoclinic ,space group Cc, and the lattice parameters are as follow: a=18.675(3)° A , b=10.3906, c=16.446(2)° A , α=90.00°, β=96.757(2)°, γ=90.00°, V=3169.2(7)° A , Z=4, R1=0.0492, ωR2=0.0983, F (000)=1280. The Zr ion is a distorted octahedron configuration coordination environment with coordination of two N atoms and four Cl atoms, and Li ion is a tetrahedron configuration with coordination of two Cl atoms and two O atoms.%以苯胺、正丁基锂和四氯化锆等为原料合成了含金属锆、锂的双核化合物（1），并通过X-ray单晶衍射，1H NMR，13C NMR对该化合物结构进行了表征。该化合物单斜晶系,Cc空间群,晶胞参数a=18.675(3),b=10.3906(14)，c=16.446(2)，α=90.00°，β=96.757(2)°,γ=90.00°,V=3169.2(7)，Z=4, R1=0.0492，ωR2=0.0983，F(000)=1280。其中，Zr(IV)与配体中的两个氮原子、本身所带的四个氯原子配位，形成变形八面体配位构型，而Li(I)与两个氯原子、溶剂乙醚分子中的氧原子配位，形成一个四面体构型。° A ° A ° A ° A
展开▼
