Two new processes of synthesizing phenyl benzoate were studied, the first method was used by benzoic acid and phenol on the condition of trichlorophosphine, yield of product 90%, The yield of the second method was 85% on the condition of catalyzing by polyphosphoric acid, by contrasting with two methods, It was not only high quality but also high yield on the condition of benzoic acid;but it was not only few pollution but also high yield and simpleness on the condition of catalyzing by polyphosphoric acid.%通过两种方法合成了苯甲酸苯酯,用苯甲酸与苯酚在三氯化磷的作用下合成苯甲酸苯酯,产率:90%;用苯甲酸与苯酚在多聚磷酸的催化作用下合成苯甲酸苯酯,产率:85%。两种方法比较:用三氯化磷反应,产品质量好,产率高;用PPA作催化剂反应,污染小,后处理简单,产率较高。
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