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Activation of Electrophile/Nucleophile Pair by a Nucleophilic and Electrophilic Solvation in a SNAr Reaction

机译：SNAr反应中亲核和亲电溶剂对亲电/亲核对的活化

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Nucleophilic aromatic substitution reactions of 4-chloroquinazoline toward aniline and hydrazine were used as a model system to experimentally show that a substrate bearing heteroatoms on the aromatic ring as substituent is able to establish intramolecular hydrogen bond which may be activated by the reaction media and/or the nature of the nucleophile.

机译：以4-氯喹唑啉对苯胺和肼的亲核芳香取代反应为模型系统，以实验表明在芳香环上带有杂原子作为取代基的底物能够建立分子内氢键，该氢键可被反应介质和/或活化亲核试剂的性质。

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期刊名称 Frontiers in Chemistry
作者
Bruno Sánchez; Cristian Calderón; Ricardo A. Tapia; Renato Contreras; Paola R. Campodónico;
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作者单位

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年(卷),期 2018(6),-1
年度 2018
页码 509
总页数 9
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
solvent effects ionic liquids catalysis anion effect preferential solvation;

机译：溶剂效应;离子液体;催化;阴离子效应;优先溶剂化;

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专利

1. Facile aromatic nucleophilic substitution (SNAr) reactions in ionic liquids: an electrophile-nucleophile dual activation by [Omim]Br for the reaction (vol 28, pg 5580, 2016) [J] . Zhang Xiao, Lu Guo-ping, Cai Chun Green chemistry . 2016,第22期

机译：离子液体中的便捷芳族亲核取代（SNAr）反应：[Omim] Br对该反应的亲电子亲核双重活化作用（第28卷，第5580页，2016年）
2. Facile aromatic nucleophilic substitution (SNAr) reactions in ionic liquids: an electrophile-nucleophile dual activation by [Omim]Br for the reaction [J] . Zhang Xiao, Lu Guo-ping, Cai Chun Green chemistry . 2016,第20期

机译：离子液体中的简便芳族亲核取代（SNAr）反应：[Omim] Br对该反应进行亲电子亲核双重活化
3. Activation of electrophileucleophile pair by a nucleophilic and electrophilic solvation in a SNAr reaction [J] . Sánchez Bruno, Calderon Cristian, Tapia Ricardo, Frontiers in Chemistry . 2018,第2008期

机译：SNAr反应中亲核和亲电溶剂对亲电/亲核对的活化
4. Towards a Prediction of Protein Reactivity against Electrophile Ligands 1. Ranking Amino Acid Side Chain Nucleophilicities [C] . Guillaume Gabant, Yoann Richer, Solene Motteau, ASMS Conference on Mass Spectrometry and Allied Topics . 2016

机译：朝向电泳配体的蛋白质反应性预测1.排名氨基酸侧链亲核
5. Utilizing allylic alcohols as both electrophiles and nucleophiles in gold-catalyzed reactions. [D] . Ketcham, John Michael. 2013

机译：在金催化的反应中同时使用烯丙醇作为亲电子试剂和亲核试剂。
6. Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles [O] . Nicolai A. Aksenov, Alexander V. Aksenov, Sergei N. Ovcharov, 2020

机译：与碳基亲核试剂反应的亲电子活化的硝基烷
7. Correction: Facile aromatic nucleophilic substitution (SNAr) reactions in ionic liquids: an electrophile–nucleophile dual activation by OmimBr for the reaction [O] . Xiao Zhang, Guo-ping Lu, Chun Cai 2016

机译：离子液体中的容易芳族亲核替代（SNAR）反应：OMIM BR进行反应的电泳 - 亲核试剂双激活

Activation of Electrophile/Nucleophile Pair by a Nucleophilic and Electrophilic Solvation in a SNAr Reaction

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